| | 1 | Author
| H. N. Öth, J. K. Nizek | Requires cookie* | | | Title
| Reduktion eines Bis(chlorphenylphosphanyl)methylids zum entsprechenden Diphosphan und Tetraphosphinan  | | | | Abstract
| R e d u ctio n o f a B is(c h lo ro p h en y lp h o sp h an y l)m e th y lid e to the C o rresp o n d in g D ip h o sp h a n e and T etraphosp h in an e F. B reitsam eter, A. S ch m id p e te r* , The bis(phosphanyl)ylides Ph3PC(PPh2)2, Ph3PC(PPhCl)2 (3) and Ph3PC(PCl2)2 have ana logous molecular structures. Details reflect the different charge transfer from the ylide center to the phosphanyl substituents. Chlorination destroys the chirality of 3. Reduction leads to the diphosphane 8 and the 1,2,4,5-tetraphosphinane 9 which are also included in the structural comparison. | | | |
Reference
| (Z. Naturforsch. 54b, 1—7 [1999]; eingegangen am 31. August 1998) | | | |
Published
| 1999 | | | |
Keywords
| Phosphonium Ylides, Negative Hyperconjugation, Phosphorus Carbon Heterocycles, Diphos-phirane, Tetraphosphinane | | | |
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| default:Reihe_B/54/ZNB-1999-54b-0001.pdf | | | | Identifier
| ZNB-1999-54b-0001 | | | | Volume
| 54 | |
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