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1Author    Dieter Rehder, Hans-Christoph Bechthold, Ahmet Keçeci, Hartwig Schmidt, Michael SiewingRequires cookie*
 Title    A Comparative Study of Metal Shielding in Low Valent Vanadium, Niobium and Manganese Complexes  
 Abstract    Variations of the metal chemical shifts <5(51 V), <5(55 Mn) and <S(93 Nb) with the para-magnetic deshielding contribution to the overall shielding are discussed in terms of influences imposed by the ligand field splitting, the nephelauxetic effect and the covalency of the metal-to-ligand bond. Complexes under investigation are isoelectronic and/or iso-structural series [M(CO)6_nL"]<i (M = V, Nb: q = —1; M = Mn: q = + 1; n = 0-6), 7? 5 -C5H5M(CO)4-KLn (M = V, Nb; n = 0-4) and r? 5 -C5H5M(L /)2L (M = V, L' = NO; M = Mn, L' = CO). L is a monodentate or l/n oligodentate phosphine. <5 varies with the point symmetry of the complex, and with ligand parameters of primarily electronic or steric origin. Generally, for weak to medium ^-interaction, there is a decrease of shielding with decreasing yr-acceptor power of the ligand, increasing ligand bulkiness, increasing ring strains in chelate structures and increasing degree of substitution. For strong ^-inter-action, the trends may be interconverted. PF3 is shown to be a slightly weaker 7r-acceptor than CO. Selected results on nuclear-spin spin coupling constants, 13 C and 31 P shielding are also presented. 
  Reference    Z. Naturforsch. 37b, 631—645 (1982); eingegangen am 25. November 1981 
  Published    1982 
  Keywords    Carbonylphosphinevanadium, Carbonylphosphineniobium, Carbonylphosphinemanganese, NMR Spectra 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0631.pdf 
 Identifier    ZNB-1982-37b-0631 
 Volume    37 
2Author    Wolf-Walther Du Mont, Mario GrenzRequires cookie*
 Title    Bis(trimethylsiloxy)tin(II): A Heterosiloxane as Soft Ligand  
 Abstract    Contrary to earlier reports the reaction of sodium trimethylsilanolate with stannous chlo-ride does not yield bis(trimethylsiloxy)tin(II) (1) but a polynuclear compound of the type Sn20(0SiMe3)2 (2). 1 is obtained from the reac-tion of stannocene with trimethylsilanole. The compound is a dimer that gives rapid exchange reactions of terminal and bridging trimethylsil-oxy groups in inert organic solvents. 
  Reference    (Z. Naturforsch. 38b, 113—114 [1983]; eingegangen am 10. September 1982) 
  Published    1983 
  Keywords    Oxastannylenes, Heterosiloxanes, NMR Spectra 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0113_n.pdf 
 Identifier    ZNB-1983-38b-0113_n 
 Volume    38 
3Author    Gilbert Brands, Alfred GollochRequires cookie*
 Title    Schwefel-Stickstoff-Verbindungen, XII [1] 19 F-NMR-und 13 C-NMR-spektroskopische Untersuchung einiger aromatisch substituierter Schwefeldiimide Sulfur-Nitrogen Compounds, XII [1] 19 F NMR and 13 C NMR Spectroscopic Investigation of Some Aromatic Substituted Sulfurdiimides  
 Abstract    i»F NMR and «C NMR spectra of the sulfur(IV)diimines R1-NSN-R2 (Ri/2 = C6H5, C6F5, C6H5S, C6F5S) and the corresponding N-sulfinylamines R!/ 2 -NSO are discussed. Chemical shifts are correlated to the electron withdrawing properties of the substituents. 
  Reference    Z. Naturforsch. 38b, 326—331 (1983); eingegangen am 20. September/7. Dezember 1982 
  Published    1983 
  Keywords    Sulfurdiimines, N-Sulfinylamines, NMR Spectra 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0326.pdf 
 Identifier    ZNB-1983-38b-0326 
 Volume    38 
4Author    ReinerM. Artens++, W. Olf-W, Alther, M. Ont, Lutz LangeRequires cookie*
 Title    Trichlorsilylierung sperriger Dialkylchlorphosphane und Tetraalkyldiphosphane mit HexachlordisiIan+ Trichlorosilylation of Bulky Dialkylchlorophosphanes and Tetraalkyldiphosphanes with Hexachlorodisilane  
 Abstract    Chlorodiisopropylphosphane reacts with hexachlorodisilane to give diisopropyl(tri-chlorosilyl)phosphane which reacts with the educt chlorophosphane to produce tetraisopro-pyldiphosphanc. Tetraisopropyldiphosphane reacts with hexachlorodisilane to provide diiso-propyl(trichlorosilyl)phosphane. With di-/m-butylchlorophosphane and tetra-/e/7-butyldi-phosphane, the corresponding reactions leading to dW£>/7-butyl(trichlorosilyl)phosphane are much slower; while the product does not react further with di-/e/7-butylchlorophosphane, it does with chlorodiisopropylphosphane. A stable 1 : 1 complex is formed from di-tert-butyl(trichlorosilylphosphane) with silver bromide. Products are characterized on the basis of analytical and 'H, l3C, 29Si and 3IP NMR data. 
  Reference    Z. Naturforsch. 46b, 1609—1612 (1991); eingegangen am 3. Juli 1991 
  Published    1991 
  Keywords    Trichlorosilylation, Chlorophosphanes Silylphosphanes, NMR Spectra 
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 TEI-XML for    default:Reihe_B/46/ZNB-1991-46b-1609.pdf 
 Identifier    ZNB-1991-46b-1609 
 Volume    46 
5Author    Jörn Müller, PetraEscarpa Gaede, Ke QiaoRequires cookie*
 Title    ^-Olefin-Iridium-Komplexe, XXII [1] C -H -Aktivierung von aromatischen und aliphatischen Solvensmolekülen RH bei der Reaktion von [Cp*IrCI2 ] 2 mit Butadienmagnesium unter Bildung von [Cp*Ir(773-C4H 7)R] sowie Kristallstruktur von [Cp*Ir(i/3-C4H 7)C6H 5] jr-Olefin Iridium Complexes, XXII [1] C -H Activation of Aromatic and Aliphatic Solvent Molecules RH in the Reaction of [Cp*IrCl2 ] 2 with Butadienemagnesium with Formation of [Cp*Ir(?;3 -C4 H 7 )R], and Crystal Structure of [Cp*Ir(773 -C4 H 7 )C6 H 5] Activation of C -H , (l-Methylallyl)(pentamethylcyclopentadienyl)iridium-a-organyl Com­ plexes  
 Abstract    Reactions of [Cp*IrCl2]2 (Cp* = ^3-C5M e5) with [MgC4H6 -2 THF]" at low temperature give [Cp*Ir(^4-C4H6)] together with [Cp*Ir(/73-C4H 7)R] compounds, the latter being formed via C -H activation of solvent molecules RH (RH = benzene, toluene, anisole, thiophene, furane, N-methylpyrrole, pentane, cyclohexane. THF). In the case of pyrrole, C -N -activation occurs. The ratio of syn and anti isomers of the 1-methylallyl com plexes as well as the sites o f C -H activation of RH were investigated by NM R spectrometry. An enantiomorphous crystal of [Cp*Ir(773-C4H7)C6Hs] was characterized by X-ray diffraction analysis which reveals trigonal planar coordination at the Ir atom and an exo, syn conformation o f the 1-methylallyl ligand. A mechanism of the reaction which involves 16-electron intermediates is discussed. The corresponding system [Cp*RhCl2]2/butadienemagnesium/RH gives only [Cp*Rh(>/4-C4H6)], and no C -H activation is observed. 
  Reference    Z. Naturforsch. 49b, 1645—1653 (1994) 
  Published    1994 
  Keywords    Synthesis, NMR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/49/ZNB-1994-49b-1645.pdf 
 Identifier    ZNB-1994-49b-1645 
 Volume    49 
6Author    Ekkehard Lindner, Günter Von AuRequires cookie*
 Title    Darstellung und Eigenschaften von und Reaktionen mit metallhaltigen Heterocyclen, VII [1] Heterolytische Spaltung der Re-Re-Bindung in den Zweikern-Anionen [(OC)4ReP(R2 )0] 2 2 ~ mit Elektrophilen - ein Weg zu Heterocyclen mit Re-C-o-Bindung Preparation and Properties of, and Reactions with, Metal-Containing Heterocycles, VII [1] Heterolytic Cleavage of the Re-Re Bond in the Binuclear Anions [(0C)4ReP(R2)0]2 2_ with Electrophiles -a Pathway to Heterocycles with Re-C a Bonds  
 Abstract    The preparation of the six-membered rhenacyclohexanes (OC)4ReP(R2)OCH2C(CH3)2CH2 (la, b) [R = CH3 (a), C6H5 (b)J is accomplished by heterolytic cleavage of the Re-Re bond in the binuclear anions [(0C)4ReP(R2)0]2 2 -with strong electrophiles like the alkane-diylbis(triflate) (CH3)2C(CH2Y)2 (Y= OSO2CF3), followed by an attack of the a>-positioned carbenium-like C atom on the phosphinite oxygen of the anion. 1 a, b insert SO2 under ring I I 
  Reference    Z. Naturforsch. 35b, 1104—1110 (1980); eingegangen am 9. Mai 1980 
  Published    1980 
  Keywords    Rhenacyclohexanes, Mechanism, S02-Insertio", X-ray, IR spectra, NMR spectra : 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1104.pdf 
 Identifier    ZNB-1980-35b-1104 
 Volume    35 
7Author    Trimethylsilyl Tetrafluorotellurates, Vi, Benno Bildstein, Walter Tötsch, Fritz Sladky, E-F=. Me, E-RRequires cookie*
 Title    Trimethylsüyl-tetrafluorotellurate(VI)  
 Abstract    The interaction of MesSiCl with eis-and trans-(HO)2TeF 4 and eis-and £ran.s-HOTeF 4 OCH 3 yields eis-and trans-(Me3SiO)2TeF 4 and eis-and <rans-Me3SiOTeF 4 OCH3, respectively, which have been characterized by NMR spectroscopy (125 Te, 29 Si, 19 F, X H). Die Trimethylsilylgruppe ist eine häufig verwen-dete Abgangsgruppe in Reaktionen mit Fluoriden: 
  Reference    Z. Naturforsch. 36b, 1542—1543 (1981); eingegangen am 22. Juli 1981 
  Published    1981 
  Keywords    Synthesis, Trimethylsilyl Tetrafluorotellurates(VI), NMR Spectra 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-1542.pdf 
 Identifier    ZNB-1981-36b-1542 
 Volume    36 
8Author    Edgar Niecke, Anke Nickloweit-Lüke, Reinhold Rüger, Bernt Krebs, Helmut GreweRequires cookie*
 Title    .2A 3 .3A 3 -Azadiphosphiridine -Synthese, Kristallstruktur und Eigenschaften 1,2 A 3 ,3 x 3 -Azadiphosphiridines -Synthesis, Crystal Structure and Proj)erties  
 Abstract    1,2 A 3 ,3 A 3 -Azadiphosphiridines are avaüable by elimination of hydrogenhalide from ß-and y-functional molecular frameworks and by 1 + 2 cycloaddition of phosphinidenes towards aminoiminophosphanes. In contrast to other three-membered phosphorus com-pounds, azadiphosphiridines decompose by 2 +1 cycloreversion to aminoiminophosphanes and phosphinidenes. The molecular structure of an azadiphosphiridine demonstrates the trans arrangement of the exocyclic ligands and the planarity of the endocyclic nitrogen. 
  Reference    Z. Naturforsch. 36b, 1566—1574 (1981); eingegangen am 13. Juli 1981 
  Published    1981 
  Keywords    Azadiphosphiridines, Cyclisation, Thermal Decomposition, NMR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-1566.pdf 
 Identifier    ZNB-1981-36b-1566 
 Volume    36 
9Author    OttoJ. Scherer, Heribert JungmannRequires cookie*
 Title    Phosphor-Ylid-Komplexe des Platins Phosphorus Ylide Complexes of Platinum  
 Abstract    The interaction of eis/trans-[Pt(PPI13) 2 (CH2CI)Cl] (1) with Ph 3 P gives the ylide complex cis-[Pt(PPh 3) 2 (CH 2 PPh 3)Cl]Cl (2), which forms cis-[Pt(PPh 3)(CH 2 PPh 3)Cl 2 ] (3) on heating in benzene. In CH 2 C1 2 , Ph 3 P is added again quanti-tatively with formation of 2. Irradiation of 3 with a 500 W lamp yields cw-Cl 2 Pt(PPh 3) 2 . The ylide complexes 4 and 6 were prepared by treatment of 3 with (Me2N) 3 P or Ph 3 As. 3 and Ph 2 P(CH 2) 2 PPh 2 form the chelate ylide com-plex 6. 
  Reference    Z. Naturforsch. 36b, 1663—1665 (1981); eingegangen am 26. August 1981 
  Published    1981 
  Keywords    Phosphorus Ylide Complexes, Synthesis, NMR Spectra 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-1663_n.pdf 
 Identifier    ZNB-1981-36b-1663_n 
 Volume    36 
10Author    Fritz Preuss, Lothar OggerRequires cookie*
 Title    Alkylvanadium( V) -Verbindungen Darstellung und NMR-spektroskopische Untersuchungen Alkylvanadium(V) Compounds S\ T nthesis and NMR Spectroscopic Studies  
 Abstract    The compounds Li["C4H9V0(0«C4H9)3], Me3SiCH2V(0<C4H9)3, (CH3)2V(OSiMe3)2 and V(0'C4Hg)4 have been prepared by reaction of esters VO(OR)3(R = J C4H9, SiMes) with lithium alkyls. RV0(0'C4H9)2 species are not formed by direct alkylation of VO(O f C4H 9)3 with LiR; albeit in small yields, these compounds (R = CH3, CH 2 SiMe3) can be synthesized however from V0(0«C4H9)2C1. The 51 V, and 13 C NMR spectra of the vanadium(V) and vanadium(IV) compounds are discussed; the constants of 51 V, iH and 51 V, 13 C coupling have been determined. 
  Reference    Z. Naturforsch. 37b, 957—964 (1982); eingegangen am 15. Februar 1982 
  Published    1982 
  Keywords    Alkylvanadium(V) Compounds, Preparation, NMR Spectra 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0957.pdf 
 Identifier    ZNB-1982-37b-0957 
 Volume    37 
11Author    OttoJ. Scherer, Klaus-Dieter KriegerRequires cookie*
 Title    Diazadiphosphetidine Platinum(O) Complexes  
 Abstract    The reaction of Pt(COD)2 with cw-[RPNCR3]2 (1), R = CH3, affords the two-coordinate platinum(O) complex PtLo (2) (L = diazadiphosphetidine 1). In benzene solution PtL2, Pt2L3 (3) and L are in equilibrium. 2 and diphenylacetylene or fumaric acid dinitrile give the platinum diazadiphosphetidine complexes LoPt(PhCCPh) (4) and L2Pt[H(NC)CC(CN)H] (5), L = 1. 
  Reference    Z. Naturforsch. 37b, 1041—1043 (1982); eingegangen am 17. Februar 1982 
  Published    1982 
  Keywords    Diazadiphosphetidine Complexes, Synthesis, Reactions, NMR Spectra 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1041.pdf 
 Identifier    ZNB-1982-37b-1041 
 Volume    37 
12Author    Barteld De Ruiter, Geert Kuipers, JanH. Bijlaart, JohanC. Van De GrampelRequires cookie*
 Title    Derivatives of NPC12(NS0C1)2 and (NPC12)2NS0C1, Part XX [1] Reactions of Some Inorganic Ring Systems with N,N' -Dimethylethylenediamine  
 Abstract    Reactions of the ring systems (NPC12)3, (NPCl2)2NSOX, and NPC12(NS0X)2 (X = Cl, Ph) with N,N'-dimethylethylenediamine lead to mono-, bis-, and tris(spirocyclic) com-pounds as the only characterizable products. The X H and 31 P NMR parameters are re-ported and briefly discussed. 
  Reference    Z. Naturforsch. 37b, 1425—1429 (1982); received June 18 1982 
  Published    1982 
  Keywords    Phosphorus-Sulfur-Nitrogen Heterocycles, Diazaphospholidines, NMR Spectra 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1425.pdf 
 Identifier    ZNB-1982-37b-1425 
 Volume    37 
13Author    Rolf Minkwitz, Rüdiger NaßRequires cookie*
 Title    Spektroskopische Untersuchungen an Monofluorammoniumsalzen Spectroscopic Studies on Monofluorammonium Salts  
 Abstract    The NMR, IR and Raman spectra of several NHaF+X -salts are reported. The prepara-tion of NH3F+SO3CI-and NH3F+SO3F-is described. 
  Reference    Z. Naturforsch. 37b, 1558—1563 (1982); eingegangen am 21. Juli 1982 
  Published    1982 
  Keywords    NMR Spectra, Raman Spectra, IR Spectra 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1558.pdf 
 Identifier    ZNB-1982-37b-1558 
 Volume    37 
14Author    Jörn Müller, Wolfgang Hähnlein, Barbara PassonRequires cookie*
 Title    TT-Olefin-Iridium-Komplexe, IX [1] Bis(?y 4 -butadien)-(7-organyl-iridium-Verbindungen TI-Olefin Iridium Complexes, IX [1] Bis(fy 4 -butadiene)-cr-organyl-iridium Compounds  
 Abstract    Complexes of the type [L2IrR] (L = butadiene, isoprene, piperylene, 1,4-and 2,3-dimethylbutadiene; R = CH3, CeHs) have been synthesized by reactions of [L2IrCl] with LiR in hexane. With L = 2,3-dimethylbutadiene, [L2IrR] compounds with higher alkyl groups R (e.g. n-C3H7, n-CjHg) can be obtained which for steric reasons are inert against ^-elimination. Th© system [L2IrCl]/L/LiAlH4 (L = 2,3-dimethylbutadiene) yields [L2IrR] with R = 2,3-dimethylbutene-2-yl. The complexes were characterized by NMR and mass spectra. 
  Reference    Z. Naturforsch. 37b, 1573—1579 (1982); eingegangen am 8. Juli 1982 
  Published    1982 
  Keywords    Synthesis, Mass Spectra, NMR Spectra, yr-Olefm Iridium Complexes 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1573.pdf 
 Identifier    ZNB-1982-37b-1573 
 Volume    37 
15Author    Herman Winter, JohanC. Van De GrampelRequires cookie*
 Title    Derivatives of NPCI^NSOCl), and (NPC12)2NS0C1, Part XXI [1]. The Synthesis of a Spiro Phosphazene Derivative of NPCl^NSOPh^  
 Abstract    The preparation of the spirocyclic compounds eis-and £rans-NP[(NPCl2)2NCH3](NSOPh)2 from eis-and Zrans-NPCl2(NSOPh)2 is described as well as the synthesis of the inter-mediates. The 31 P NMR data are discussed. 
  Reference    (Z. Naturforsch. 38b, 7 [1983]; received August 23 1982) 
  Published    1983 
  Keywords    Phosphorus-Sulfur-Nitrogen Heterocycles, Spirocyclic Derivatives, NMR Spectra 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0007.pdf 
 Identifier    ZNB-1983-38b-0007 
 Volume    38 
16Author    Dieter Weber, Karl Peters, Hans Georg, Schnering, Ekkehard FluckRequires cookie*
 Title    Kristallstruktur yon Pyrrolidinium-bis(diisopropylphosphinoyl)phosphid, einem System mit zweifach koordiniertem Phosphor Crystal Structure of Pyrrolidinium-bis(diisopropylphosphinoyl)phosphide, a System with Bicoordinated Phosphorus  
 Abstract    Pyrrolidinium-bis(diisopropylphosphinoyl)phosphide crystallizes triclinically in the space group Pi with a = 1019.6(8), b = 1271.5(4), c = 999.5(7) pm, a = 100.90(5)°, ß = 91.24(5)°, y = 99.10(5)° and Z = 2 formula units. The mean P-P bond length is 212.2 pm and hence shorter than in derivates in which the electron pairs of the bicoordi-nated phosphorus atom are bonded to one or two M(CO)5-groups. Additional p.-z-d* bonding explains the shortening of the P-P bond. 
  Reference    Z. Naturforsch. 38b, 208—211 (1983); eingegangen am 13. Oktober 1982 
  Published    1983 
  Keywords    Pyrrolidinium-bis(diisopropylphosphinoyl)phosphide, Crystal Structure, NMR Spectra 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0208.pdf 
 Identifier    ZNB-1983-38b-0208 
 Volume    38 
17Author    K. Barlos, Heinrich NöthRequires cookie*
 Title    Beiträge zur Chemie des Bors, CVIII [1] Synthese und Konformation yon N.N'-Bis(boryl)-N.N'-dimethylhydrazinen Contributions to the Chemistry of Boron, CVIII [1] Synthesis and Conformation of N,N , -Bis(boryl)-N,N'-dimethylhydrazines N,N'-Bis(methylboryl)-N,N'-dimethyl-hydrazine, N,N'-Bis(dichlor-boryl)-N,N  
  Reference    (Z. Naturforsch. 35b, 125—132 [1980]; eingegangen am 10. August 1979) 
  Published    1980 
  Keywords    -dimethyl-hydrazine, Conformation, NMR Spectra, PE Spectra 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0125.pdf 
 Identifier    ZNB-1980-35b-0125 
 Volume    35 
18Author    Herbert Meier, Hansjörg Gugel, Margret Barth, Udo PlückenRequires cookie*
 Title    Konformationsuntersuchungen an benzokondensierten Achtringen Conformation Analysis of Benzo-Condensed Eight-Membered Rings  
 Abstract    The annellation of 1-4 benzene rings to carbocyclic 8-rings increases stepwise the activation barrier for the ring inversion. A drastic consequence of the steric hindrance in the transition state is the rigidity of 9,10-dihydro-tribenzo[a,c,e]cyclooctenes at room temperature. With the aid of a complete analysis of the iH NMR spectra a decision is possible between fixed C2-conformations (e.g. 8) and Cs-conformations (e.g. 9). 
  Reference    Z. Naturforsch. 35b, 477—481 (1980); eingegangen am 13. Dezember 1979 
  Published    1980 
  Keywords    Ring Inversion, NMR Spectra, Lanthanoid Shift Measurements 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0477.pdf 
 Identifier    ZNB-1980-35b-0477 
 Volume    35 
19Author    Herbert Schumann, Manfred MeissnerRequires cookie*
 Title    Organometallphosphin-substituierte Übergangsmetallkomplexe, XXVI [1] Diearbonyl-nitrosyl-organometaUphosphin-kobalt-Komplexe Organometalphosphine-Substituted Transition Metal Complexes, XXVI [1] Dicarbonyl Nitrosjd Organometal Phosphine Cobalt Complexes  
 Abstract    The reactions of tricarbonyl nitrosyl cobalt with tri-feri-butylphosphine, di(teri-butyl)-trimethylsilyl-, -germyl-, -stannylphosphine, £er£-butyl-bis(trimethylsilyl)-, -(germyl)-, -(stannyl)phosphine, as well as with tris(trimethylsilyl)-, -(germyl)-, and -(stannyl-phosphine result in the elimination of one CO-ligand and the formation of corresponding dicarbonyl-nitrosyl-organometal phosphine cobalt complexes. The NMR spectra of the products are reported and discussed. 
  Reference    Z. Naturforsch. 35b, 594—598 (1980); eingegangen am 5. Dezember 1979 
  Published    1980 
  Keywords    Organometal Phosphines, Dicarbonyl-nitrosyl Cobalt Complexes, NMR Spectra 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0594.pdf 
 Identifier    ZNB-1980-35b-0594 
 Volume    35 
20Author    W. PetzRequires cookie*
 Title    Darstellung von Eisentetracarbonylkomplexen mit Thioacetamiden als Liganden Preparation of Iron Tetracarbonyl Complexes with Thioacetamides as Ligands  
 Abstract    The thioacetamids S = C(CH3)(NHR) (R = H, la; R = Ph, lb) react with Fe2(CO)9 to form the iron tetracarbonyl complexes 2 and 3 with S-bonded ligands. IR, X H, 13 C and mass spectra of these new compounds are reported. 
  Reference    Z. Naturforsch. 35b, 860—862 (1980); eingegangen am 17. März 1980 
  Published    1980 
  Keywords    Iron Carbonyl Complexes, Thioacetamid Ligands, NMR Spectra 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0860.pdf 
 Identifier    ZNB-1980-35b-0860 
 Volume    35