| | 1 | Author
| Peter Dierkes, Gerlinde Frenzen, Sigrid Wocadlo, W. Erner Massa, Stefan Berger, Jürgen Pebler, Kurt Dehnicke | Requires cookie* | | | Title
| Komplexe des Typs [MCl4(SEt2)2] mit M = Mo und W. Kristallstrukturen, NMR-Spektren und magnetisches Verhalten [MCl4(SE t2)2] Complexes with M = Mo and W. Crystal Structures, NMR Spectra, and Magnetic Behaviour  | | | | Abstract
| The crystal structures of the thioether complexes [MCl4(SEt2)2] with M = Mo and W have been solved by X-ray methods. Both compounds crystallize isotypically in the triclinic space group P I with two formula units per cell unit. The metal atoms are octahedrally coordinated by four chlorine atoms and by the two sulfur atoms of the thioether molecules in trans position (symmetry Q) with bond lengths (average): M o -C l 233.1, M o -S 253.4, W -C l 233.1, and W -S 251.7 pm. Both complexes were also characterized by !H and 13C NM R spectro scopy as well as by measurement of the magnetic susceptibilities in the tem perature range from 1.8 to 350 K. | | | |
Reference
| Z. Naturforsch. 50b, 159—167 (1995); eingegangen am 23. August 1994 | | | |
Published
| 1995 | | | |
Keywords
| D iethylthioethers of Molybdenum and Tungsten, Crystal Structure, NMR Spectra, Magnetic Susceptibility | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/50/ZNB-1995-50b-0159.pdf | | | | Identifier
| ZNB-1995-50b-0159 | | | | Volume
| 50 | |
|
