| | 1 | Author
| ReinerM. Artens++, W. Olf-W, Alther, M. Ont, Lutz Lange | Requires cookie* | | | Title
| Trichlorsilylierung sperriger Dialkylchlorphosphane und Tetraalkyldiphosphane mit HexachlordisiIan+ Trichlorosilylation of Bulky Dialkylchlorophosphanes and Tetraalkyldiphosphanes with Hexachlorodisilane  | | | | Abstract
| Chlorodiisopropylphosphane reacts with hexachlorodisilane to give diisopropyl(tri-chlorosilyl)phosphane which reacts with the educt chlorophosphane to produce tetraisopro-pyldiphosphanc. Tetraisopropyldiphosphane reacts with hexachlorodisilane to provide diiso-propyl(trichlorosilyl)phosphane. With di-/m-butylchlorophosphane and tetra-/e/7-butyldi-phosphane, the corresponding reactions leading to dW£>/7-butyl(trichlorosilyl)phosphane are much slower; while the product does not react further with di-/e/7-butylchlorophosphane, it does with chlorodiisopropylphosphane. A stable 1 : 1 complex is formed from di-tert-butyl(trichlorosilylphosphane) with silver bromide. Products are characterized on the basis of analytical and 'H, l3C, 29Si and 3IP NMR data. | | | |
Reference
| Z. Naturforsch. 46b, 1609—1612 (1991); eingegangen am 3. Juli 1991 | | | |
Published
| 1991 | | | |
Keywords
| Trichlorosilylation, Chlorophosphanes Silylphosphanes, NMR Spectra | | | |
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| default:Reihe_B/46/ZNB-1991-46b-1609.pdf | | | | Identifier
| ZNB-1991-46b-1609 | | | | Volume
| 46 | |
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