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'NMR Spectra' in keywords Facet Publication Year 1983 [X]
Facet section ZfN Section B:Volume 038 [X]

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1	Author	Wolf-Walther Du Mont, Mario Grenz	Requires cookie*
	Title	Bis(trimethylsiloxy)tin(II): A Heterosiloxane as Soft Ligand
	Abstract	Contrary to earlier reports the reaction of sodium trimethylsilanolate with stannous chlo-ride does not yield bis(trimethylsiloxy)tin(II) (1) but a polynuclear compound of the type Sn20(0SiMe3)2 (2). 1 is obtained from the reac-tion of stannocene with trimethylsilanole. The compound is a dimer that gives rapid exchange reactions of terminal and bridging trimethylsil-oxy groups in inert organic solvents.
	Reference	(Z. Naturforsch. 38b, 113—114 [1983]; eingegangen am 10. September 1982)
	Published	1983
	Keywords	Oxastannylenes, Heterosiloxanes, NMR Spectra
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-0113_n.pdf
	Identifier	ZNB-1983-38b-0113_n
	Volume	38

2	Author	Gilbert Brands, Alfred Golloch	Requires cookie*
	Title	Schwefel-Stickstoff-Verbindungen, XII [1] 19 F-NMR-und 13 C-NMR-spektroskopische Untersuchung einiger aromatisch substituierter Schwefeldiimide Sulfur-Nitrogen Compounds, XII [1] 19 F NMR and 13 C NMR Spectroscopic Investigation of Some Aromatic Substituted Sulfurdiimides
	Abstract	i»F NMR and «C NMR spectra of the sulfur(IV)diimines R1-NSN-R2 (Ri/2 = C6H5, C6F5, C6H5S, C6F5S) and the corresponding N-sulfinylamines R!/ 2 -NSO are discussed. Chemical shifts are correlated to the electron withdrawing properties of the substituents.
	Reference	Z. Naturforsch. 38b, 326—331 (1983); eingegangen am 20. September/7. Dezember 1982
	Published	1983
	Keywords	Sulfurdiimines, N-Sulfinylamines, NMR Spectra
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-0326.pdf
	Identifier	ZNB-1983-38b-0326
	Volume	38

3	Author	Herman Winter, JohanC. Van De Grampel	Requires cookie*
	Title	Derivatives of NPCI^NSOCl), and (NPC12)2NS0C1, Part XXI [1]. The Synthesis of a Spiro Phosphazene Derivative of NPCl^NSOPh^
	Abstract	The preparation of the spirocyclic compounds eis-and £rans-NP[(NPCl2)2NCH3](NSOPh)2 from eis-and Zrans-NPCl2(NSOPh)2 is described as well as the synthesis of the inter-mediates. The 31 P NMR data are discussed.
	Reference	(Z. Naturforsch. 38b, 7 [1983]; received August 23 1982)
	Published	1983
	Keywords	Phosphorus-Sulfur-Nitrogen Heterocycles, Spirocyclic Derivatives, NMR Spectra
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-0007.pdf
	Identifier	ZNB-1983-38b-0007
	Volume	38

4	Author	Dieter Weber, Karl Peters, Hans Georg, Schnering, Ekkehard Fluck	Requires cookie*
	Title	Kristallstruktur yon Pyrrolidinium-bis(diisopropylphosphinoyl)phosphid, einem System mit zweifach koordiniertem Phosphor Crystal Structure of Pyrrolidinium-bis(diisopropylphosphinoyl)phosphide, a System with Bicoordinated Phosphorus
	Abstract	Pyrrolidinium-bis(diisopropylphosphinoyl)phosphide crystallizes triclinically in the space group Pi with a = 1019.6(8), b = 1271.5(4), c = 999.5(7) pm, a = 100.90(5)°, ß = 91.24(5)°, y = 99.10(5)° and Z = 2 formula units. The mean P-P bond length is 212.2 pm and hence shorter than in derivates in which the electron pairs of the bicoordi-nated phosphorus atom are bonded to one or two M(CO)5-groups. Additional p.-z-d* bonding explains the shortening of the P-P bond.
	Reference	Z. Naturforsch. 38b, 208—211 (1983); eingegangen am 13. Oktober 1982
	Published	1983
	Keywords	Pyrrolidinium-bis(diisopropylphosphinoyl)phosphide, Crystal Structure, NMR Spectra
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-0208.pdf
	Identifier	ZNB-1983-38b-0208
	Volume	38

5	Author	Herbert Schumann, Karl-Heinz Köhricht, Manfred Meißner	Requires cookie*
	Title	Organometallphosphin-substituierte Übergangsmetallkomplexe, XIX [1] Carbonyl-dinitrosyl-organometallphosphin-eisen-Komplexe Organometalphosphine-substituted Transition Metal Complexes, XIX [1] Carbonyl Dinitrosyl Organometalphosphine Iron Complexes Die Komplexe der Pseudonickelcarbonyl-Serie
	Abstract	The reactions of dicarbonyl dinitrosyl iron with tri-fertf-butylphosphine, di(feri-butyl)-trimethylsilyl-, -germyl-, -stannyl-phosphine, ferZ-butyl-bis(trimethylsilyl)-, -(germyl)-, -(stannyl)phosphine, as well as with tris(trimethylsilyl)-, -(germyl)-, and -(stannyl)phos-phine result in the elimination of one CO ligand and the formation of the corresponding carbonyl dinitrosyl organometalphosphine iron complexes. The IR, X H, 31 P, 13 C, and 119 Sn NMR spectra of the new complexes are reported and discussed.
	Reference	Z. Naturforsch. 38b, 705—710 (1983); eingegangen am 22. Februar 1983
	Published	1983
	Keywords	Organometal Phosphines, Carbonyl Dinitrosyl Iron Complexes, NMR Spectra
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-0705.pdf
	Identifier	ZNB-1983-38b-0705
	Volume	38

6	Author	Fritz Seel, Norbert Klein	Requires cookie*
	Title	N-Methylcarbamoylphosphate, I. Synthese N-Methylcarbamoyl Phosphates, I. Synthesis
	Abstract	Solutions of mono-and bis-N-methylcarbamoyl phosphates in non-aqueous solvents [e.g. acetonitrile, dimethyl formamide, chloroform) and, surprisingly, even in water are readily obtained by the reaction of methyl isocyanate with the solution of an appropriate mono-or dihydrogenphosphate. The course of the reactions and the limited stability of N-methylcarbamoyl phosphate ions in solutions can be monitored through 31 P NMR measurements. Various types of compounds, including a coordination compound of cobalt could.be isolated in crystalline form: [Et3NH]HX, KHX, NH4HX, Na2X • H20, MgX • 4 H20, CaX • H20, SrX • 2 HaO, BaX • H20, ZnX • 5 H20, CdX • 2 H20, [(NH3)5COX]C104, [EtsNHjY, AgY • MeCN, X = MeNHC(0)0P03, Y = [MeNHC(0) 0]2P02.
	Reference	Z. Naturforsch. 38b, 797—803 (1983); eingegangen am 24. Februar 1983
	Published	1983
	Keywords	N-Methylcarbamoyl Phosphates, Preparation, NMR Spectra
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-0797.pdf
	Identifier	ZNB-1983-38b-0797
	Volume	38

7	Author	Wieland Krüger, Michael Sell, Reinhard Schmutzler	Requires cookie*
	Title	A New Synthesis of Organodifluorophosphites and their Reactions with Platinum(II) Complexes
	Abstract	Alkyldifluorophosphites, ROPF2 (R = ^-substituted benzyl group, neopentyl, 1-ada-mantyl) have been obtained by a new method, involving reaction of the appropriate alkyl trimethylsilylether, ROSiMe3 with chlorodifluorophosphine, PF2C1. Reactions of these difluorophosphites with platinum(II) complexes of the type [LaPtCla] (L = PEt3, PPI13) led to products such as irans-[L2PtCl(POF2)] and {[p-XC6H4CH2PPh3]+}2[Pt(POF2)4] 2 -, (X = H, Me, Cl, N02). The ease of carbon-oxygen cleavage in ROPF2 is characteristically related to the nature of the leaving group, R.
	Reference	Z. Naturforsch. 38b, 1074—1080 (1983); received April 25 1983
	Published	1983
	Keywords	Organodifluorophosphites, Difluorophosphonate Complexes, Platinum, NMR Spectra
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	Identifier	ZNB-1983-38b-1074
	Volume	38

8	Author	Angelika Sebald, Bernd Wrackmeyer	Requires cookie*
	Title	Bequeme Synthese von eis-1,2- Bis(diphenylphosphino)ethanplatin(II)- acetyliden Convenient Synthesis of m-1,2-Bis(diphen3dphosphino)- ethane-platinum (II) -acetylides
	Abstract	The title compounds (1) are obtained in quantitative yield from the reaction between dppePtCl2 (2) and alkynyl stannanes (CH3)3Sn-C=C-R (8) or (CH3)2Sn(C=C-R)2 (4) in boiling tetrahydrofurane. The complexes 1 have been characterised by multinuclear NMR PC, 31 P, 195 Pt).
	Reference	Z. Naturforsch. 38b, 1156—1158 (1983); eingegangen am 3. Juni 1983
	Published	1983
	Keywords	Platinum(II)-acetylides, Synthesis, NMR Spectra
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-1156_n.pdf
	Identifier	ZNB-1983-38b-1156_n
	Volume	38

9	Author	Alfred Schmidpeter, Hubert Klehr	Requires cookie*
	Title	Überführung von Triazaphospholen in Diazaphosphole durch Acetylenaddition/Nitrileliminierung [1] Conversion of Triazaphospholes into Diazaphospholes by Acetylene Addition/Nitrile Elimination [1]
	Abstract	Acetylene di-and (less easily) monocarboxylic esters replace nitriles from the 4,5-position of 1,2,4,3-triazaphosphole rings to give carboxyl derivatives of 1,2,3-diaza-phospholes, presumably by a cycloaddition/cycloreversion mechanism. In cases with a mobile N-substituent alternatively the loss of N2 seemed feasible, but was normally not observed.
	Reference	Z. Naturforsch. 38b, 1484—1487 (1983); eingegangen am 7. Juli 1983
	Published	1983
	Keywords	Dicoordinate Phosphorus, Azaphospholes, Cycloaddition, Cycloreversion, NMR Spectra
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-1484.pdf
	Identifier	ZNB-1983-38b-1484
	Volume	38

10	Author	Wilfried Peters, Gerhard Hagele	Requires cookie*
	Title	Kernresonanzspektroskopische Untersuchungen an Organophosphorverbindungen - Thiophosphorylbromide RR P(S)Br: R,R =CH3, C2H5, f-C3H7, t-C4H9 NMR Studies on Organophosphorous Compounds -Thiophosphorylbromides RR'P(S)Br
	Abstract	NMR spectra of dialkylthiophosphoryl bromides RR'P(S)Br are analyzed. Methods are demonstrated for C2H5(t-C3H7)P(S)Br. A correlation between <53ip in the 31 P NMR spectra and the number of y3-methyl groups is discussed.
	Reference	(Z. Naturforsch. 38b, 96—102 [1983]; eingegangen am 23. August 1982)
	Published	1983
	Keywords	Dialkylthiophosphoryl Bromides, NMR Spectra, X H NMR Spectra, 31 P NMR Spectra
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-0096.pdf
	Identifier	ZNB-1983-38b-0096
	Volume	38

11	Author	I. Kostova, I. Ognyanov	Requires cookie*
	Title	Preparation and Stereochemistry of 12a-Hydroxymethyl Derivatives of Rotenone and Amorphigenin
	Abstract	A convenient method for the preparation of 12a-hydroxymethyl derivatives of rotenone 1 and amorphigenin 2, possibly applicable to other rotenoids with activated 12a-hydrogen atom is described. The stereochemistry of the products is discussed.
	Reference	Z. Naturforsch. 38b, 761—763 (1983); received October 8 1982/February 14 1983
	Published	1983
	Keywords	12a-Hydroxymethyl Rotenoids, Rotenone, Amorphigenin, Absolute Stereochemistry, NMR Spectra
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	Identifier	ZNB-1983-38b-0761
	Volume	38

12	Author	Umlagerung Synthese, Eigenschaften Diphenylphosphinosubstituierter Uracile, Jochen Ellermann, AlfonsA M Demuth	Requires cookie*
	Title	Chemie polyfunktioneller Moleküle, 74 [1] [1] Synthesis, Rearrangement and Properties of Diphenylphosphino Substituted Uracils
	Abstract	5-Bromo-uracil (2) with chloro-diphenylphosphine and triethylamine gives 5-bromo-N(1),N(3)-bis(diphenylphosphino)-uracil (3). In moist acetone, 3 is hydrolyzed to 5-bromo-N(l)-diphenylphosphino-uracil (4). 3 reacts with n-butyllithium under rearrangement and, with HCl, under elimination of a PPh2-group, forms C(5)-diphenylphosphino-uracil (7 a). Recrystallization of 7 a from ethanol yields the ethanol-1:1-adduct 7 b. Heating of 7 a in dimethylsulfoxide with D20 yields the N(l),N(3)-dideutero-C(5)-diphenylphosphino-uracil (7 c). All compounds were characterized by infrared, Raman, iH, 31 P NMR and mass spectra. 7 a shows a very small antitumor activity.
	Reference	Z. Naturforsch. 38b, 1165—1172 (1983); eingegangen am 19. Mai 1983
	Published	1983
	Keywords	Diphenylphosphino Substituted Uracils, Rearrangement, NMR Spectra, Vibrational Spectra, Mass Spectra
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	Identifier	ZNB-1983-38b-1165
	Volume	38

13	Author	Matthias Moll, Behrens* Werner Helmut, Günther Popp, WolfPeter Liehr, Fehlhammer	Requires cookie*
	Title	Über das [C7H7Fe2(CO)5]--Anion (C7H7 = Cycloheptatrienyl) About the [C7H7Fe2(CO)5]--Anion (C7H7 = Cycloheptatrienyl)
	Abstract	The extremely unstable anionic complex [C7H7Fe2(CO)6]~ (C7H7 = cycloheptatrienyl) which decomposes in polar solvents under CO elimination to give [C7H7Fe2(CO)s]~ can be prepared by deprotonation of C7H8Fe2(CO)6 (C7H8 = cycloheptatriene) with NaN(SiMe3)2 in CßHe-The NMR spectra of [C7H7Fe2(CO)5]~ show the highly fluctional character of this anion in solution. The X-ray structural parameters of Ph4As[C7H7Fe2(CO)5] (space group P2i/n) can be interpreted in terms of a rotation of the tub shaped C7H7 ring against the CO bridged Fe2(CO)5 fragment in the solid state. Consequently, each iron atom is alternatingly rj 3 -or ^-coordinated to the allyl anion and the diene part, respectively, of the anionic 8n system of the cycloheptatrienyl ring.
	Reference	Z. Naturforsch. 38b, 1446—1453 (1983); eingegangen am 7. Juni 1983
	Published	1983
	Keywords	Cycloheptatrienyl Pentacarbonyl Diferrate, IR Spectra, NMR Spectra, X-Ray
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	Identifier	ZNB-1983-38b-1446
	Volume	38

14	Author	Borislav Bogdanović, Martin Rubach, Klaus Seevogel	Requires cookie*
	Title	?f-Allyl-hydrogensulfidopalladium-und -platin-Komplexe ?7 3 -Allylmetal-Sulfur Complexes, IV [1] ?y 3 -A]lyl-hydrogensulfidopalladium and -platinum Complexes
	Reference	Z. Naturforsch. 38b, 592—598 (1983); eingegangen am 28. Dezember 1982
	Published	1983
	Keywords	r/ 3 -Allyl-hydrogerisulfklopalladium Complexes, r/ 3 -Allyl-hydrogensulfidoplatinum Complexes, IR Spectra, Raman Spectra, NMR Spectra
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-0592.pdf
	Identifier	ZNB-1983-38b-0592
	Volume	38

15	Author	Jörn Müller, Rainer Stock, Joachim Pickardt	Requires cookie*
	Title	Complex Formation of Rhodium with 6.6-Dimethylfulvene
	Abstract	Reaction of [(nbd)RhCl]2 (nbd = nor bornadiene) with CH3Li and 6.6-dimethylfulvene yields (nbd)Rh(2-propenylcyclopentadienyl). (cod)Rh(Cl)P(CH3)3 (cod = 1.5-cycloocta-diene), obtained by cleavage of [(cod)RhCl]2 with P(CH3)3, reacts with 6.6-dimethyl-fulvene and CH3Li or i-C3Ü7MgBr with substitution of cod by dimeric fulvene ligands the nature of which depends on the alkyl reagent. The new complexes were characterized by NMR spectra and in one case by X-ray diffraction analysis.
	Reference	Z. Naturforsch. 38b, 1454—1459 (1983); eingegangen am 28. Juni 1983
	Published	1983
	Keywords	Rhodium Complexes with Monomeric and Dimeric Fulvene Ligands, Synthesis, NMR Spectra, X-Ray
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	Identifier	ZNB-1983-38b-1454
	Volume	38

16	Author	Jochen Ellermann, AlfonsA M Demuth	Requires cookie*
	Title	Chemistry of Poly functional Molecules, 75 [1] The Reaction of 5-Bromo-uracil with Sodium Diphenylphosphide
	Abstract	5-Bromo-uracil (1) reacts with sodium diphenylphosphide or a mixture of sodium diphenylphosphide and sodium amide in liquid ammonia to give sodium 5-bromo-uracilate (5 a). From water 5 a crystallizes with one mole H2O yielding 5b. Treatment of 5 a with D2O yields sodium 5-bromo-N-deutero-uracilate-D20 (1/1) (5 c). With chlorodiphenyl-phosphine 5a forms 1-diphenylphosphino-uracil (2). 5a, b, c show N(l)-N(3)-(H/D)-tauto-merism in concentrated D2O solutions already, but in DMSO or Dö-DMSO only in dilute solutions. All the compounds were characterized by infrared, Raman, X H NMR, UV spectra and conductometry.
	Reference	Z. Naturforsch. 38b, 1568—1574 (1983); eingegangen am 6. Juni/2. August 1983
	Published	1983
	Keywords	Sodium 5-Bromo-uracilates, Deutero Derivatives, Tautomerism, NMR Spectra, UV Spectra, Vibrational Spectra
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	Identifier	ZNB-1983-38b-1568
	Volume	38