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'NMR Data' in keywords Facet   Publication Year 1983  [X]
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1983[X]
1Author    0. Ch, Ch, Joseph Grobe, Nikolaos VoulgarakisRequires cookie*
 Title    Atran-analoge Verbindungen des Typs Me2Si-Y-M Me2(OCH2CH2)NMe m I I V 1 ) Atrane Analogous Compounds of Type Me2Si-Y-M'Me2(OCH2CH2)NMe ! I (I) 0 CH 2 CH 2  
 Abstract    Heterocyclic ring compounds of type I (compounds 9 and 10) have been prepared by condensation reactions of a,co-difunctional derivatives XMe2SiCH2M'Me2X (X = Cl, NMe2; M' — Si, Sn) with N-methyldiethanolamine using the "Dilution Principle". The starting compounds XMe2SiCH2M'Me2X are obtained by reacting XMe2SiCH2MgCl with ClM'Me2X (Scheme, Abb. 1). The existence of transanular N-*Si or N->M' interactions depends on the N-M distance and the acidity of the acceptor atoms. In order to clarify the weight of these factors acyclic analoga of compounds 9 and 10 have been prepared. In den letzten 20 Jahren wurden verschiedene anorganische Ester des Di-bzw. Triethanolamins sowie Derivate des Typs R"_3M(OCH2CH2)3N und R"_2M(OCH2CH2)2NR 
  Reference    Z. Naturforsch. 38b, 269—279 (1983); eingegangen am 23. August 1982 
  Published    1983 
  Keywords    Silatrane, Stannatrane, Transanular N-^M-Interaction, NMR Data 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0269.pdf 
 Identifier    ZNB-1983-38b-0269 
 Volume    38