| | 1 | Author
| Katja Heinze, Gottfried Huttner, Laszlo Zsolnai | Requires cookie* | | | Title
| Tuning the Energy of the NIR Absorption of Dinuclear Triphos-Cobalt-Complexes  | | | | Abstract
| Dinuclear Co(III) complexes of the type [(triphos)Co(C6X2Z' Z2Z3Z4)Co(triphos)]2+ (Z1 ~4 = O, NR, S; R = H, Me; X = H, Cl, Br, I; 1 -62+) have been prepared and characterized by MS, IR, NMR, cyclovoltammetric and UV/VIS/NIR measurements and by X-ray analyses (12+, 3a2+ and 42+). Their redox behaviour and the energy of their low energy LMCT bands was studied and compared to the properties of the mononuclear complexes [(triphos)Co(C6H4Z 'Z 2)]+ (Z1-2 = O, NH, S). | | | |
Reference
| Z. Naturforsch. 54b, 1147—1154 (1999); received June 2 1999 | | | |
Published
| 1999 | | | |
Keywords
| Dinuclear Complexes, NIR Dyes, Cobalt, Tripodal Ligands, Bridging Ligands | | | |
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| default:Reihe_B/54/ZNB-1999-54b-1147.pdf | | | | Identifier
| ZNB-1999-54b-1147 | | | | Volume
| 54 | |
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