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'N' in keywords Facet section ZfN Section B [X]

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1	Author	ThomasK. Aukorat, Reinhard Schmutzler	Requires cookie*
	Title	N,N',N'-Trimethylethylendiamin-substituierte Phosphor(III)-Verbindungen und deren Oxidation zu Derivaten mit tetra-und pentakoordiniertem Phosphor N,N',N'-Trim ethylethylenediam ine-Substituted Phosphorus(III) Com pounds and their Oxidation to Derivatives with Four-and Five-Coordinated Phosphorus
	Abstract	A study was made o f the intramolecular donor-acceptor interaction in N ,N',N'-trim ethyl-ethylenediamine-substituted phosphorus com pounds, involving A3-, A4-and A5-phosphorus atom s, as a function o f the nature o f the substituents at phosphorus. The reaction o f N-trim ethylsilyl-N,N',N'-trim ethylethylenediam ine (1) with (Pr'0)2PCl furnished the acyclic, trimethylethylenediamine-substituted phosphorus(III) compound 4. There is no N M R spec troscopic evidence for an intramolecular donor-acceptor interaction between the phosphorus atom and the nitrogen atom o f the dim ethylam ino group in 4. The oxidation o f the trivalent phosphorus atom in 4 and in the related com pound 5 by sulfur, selenium, tetrachloro-o-benzoquinone, and hexafluoroacetone led to the corresponding A4P com pounds 6 -9 and to the A5P com pounds 10 and 11. N o intramolecular donor-acceptor interaction could be detected in any o f these products. There was no reaction between 5 and elemental tellurium. The reac tion products were characterized by N M R spectroscopy, mass spectrometry, and by elemental analysis.
	Reference	Z. Naturforsch. 47b, 275 (1992); eingegangen am 29. August 1991
	Published	1992
	Keywords	N, N', N'-Trim ethylethylenediam ine, D o n o r-Acceptor Interaction, Oxidizing Agents, N M R Spectra, M ass Spectra
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	TEI-XML for	default:Reihe_B/47/ZNB-1992-47b-0275.pdf
	Identifier	ZNB-1992-47b-0275
	Volume	47

2	Author	Thom As, K. Aukorat, PeterG. Jones, Reinhard Schmutzler	Requires cookie*
	Title	Das 7,8-Benzo-5-chloro-1,4,4-trimethyl-l-aza-4-azonia-6,9-dioxa-5 A5-phospha- spiro[4.4]nonanyl-Kation: Röntgenstrukturanalyse und temperaturabhängige ^ -N M R -Spektren4]nonanyl Cation: X-Ray Crystal Structure Determination and Variable 'H NMR Spectra
	Abstract	The 7,8-Benzo-5-chloro-1,4,4-trimethyl-1 -aza-4-azonia-6,9-dioxa-5/l5-phosphaspiro[4. The 'H N M R spectrum o f the spirophosphorane 3 at room temperature indicates dynamic behaviour o f the cation. The low-temperature 'H N M R spectra o f 3 exhibit two sets o f dou blets for the protons o f the diastereotopic N (C H 3)2 groups. The free enthalpy o f activation for the dynamic process was determined (58.6 KJ/mole). In the reaction o f 3 with sodium tetra-phenylborate the crystalline com pound, 4, involving the non-coordinating anion, [B(C6H 5)4]~, was obtained. The X-ray crystal structure analysis o f 4 reveals the presence o f a five-membered ring, formally as a result o f intramolecular donor-acceptor interaction between the nitrogen atom o f the N (C H 3)2 group and phosphorus. The geometry at phosphorus deviates som ewhat from ideal trigonal bipyramidal.
	Reference	Z. Naturforsch. 47b, 755 (1992); eingegangen am 9. September 1991
	Published	1992
	Keywords	N, N', N'-Trim ethylethylenediam ine, A zonium Salt, Donor-Acceptor-Interaction, Temperature-Dependent N M R Spectra, X-Ray Crystal Structure
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	TEI-XML for	default:Reihe_B/47/ZNB-1992-47b-0755.pdf
	Identifier	ZNB-1992-47b-0755
	Volume	47

3	Author	R. Olf Minkwitz, Jens Jakob	Requires cookie*
	Title	Uber die Bildung von N,N-Bistrifluormethylhydroxylammoniumsalzen (CF3)2N(X)OX+MF6-(X = H, D; M = As, Sb) On the Formation o f N,N-Bistrifluoromethylhydroxylammonium Salts (CF3)2N(X)O X+MF6-(X = H, D; M = As, Sb)
	Abstract	The preparation of the N,N-Bistrifluoromethylhydroxylammonium hexafluorometallates (CF3)2N(X)OX+MF6~ (X = H, D; M = As, Sb) is reported. The new compounds were cha racterized by IR, Raman, Mass, 'H , ,9F and l3C NM R spectroscopy. In addition we present our approach to the preparation of H-subsituted N,N-Bistrifluoromethylhydroxylammonium hexafluorometallates (C F ^ N (Y)O H +M F6~ (Y = C H 3, Cl, F; M = As, Sb).
	Reference	Z. Naturforsch. 52b, 958—964 (1997); eingegangen am 12. Mai 1997
	Published	1997
	Keywords	N, N-Bistrifluoromethylhydroxylammonium Hexafluoroarsenate, N, N-Bistrifluoromethylhydr-oxylammonium Hexafluoroantimonate, Vibrational Spectra, NMR Spectra, Mass Spectra
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	TEI-XML for	default:Reihe_B/52/ZNB-1997-52b-0958.pdf
	Identifier	ZNB-1997-52b-0958
	Volume	52

4	Author	Christina Ergezinger, Frank Weller, Kurt Dehnicke	Requires cookie*
	Title	Amidinatokomplexe von Bor, Aluminium, Gallium, Indium und Zinn Die Kristallstrukturen von Ph-C(NSiMe 3 ) 2 AICI 2 und Ph-C(NSiMe 3 ) 2 SnCl 3 Amidinato Complexes of Boron, Aluminium, Gallium, Indium, and Tin The Crystal Structures of Ph-C(NSiMe 3 ) 2 AlCl 2 and Ph-C(NSiMe 3 ) 2 SnCl 3
	Abstract	The trichlorides of aluminium, gallium, and indium, as well as boron tribromide and tin tetra-chloride react with N,N,N'-tris(trimethylsilyl)benzamidine to form the monomeric N.N'-bis-(trimethylsilyl)benzamidinato complexes Ph-C(NSiMe,) 2 MX 2 (M = B, Al. Ga, In; X = Cl, Br) and Ph —C(NSiMe 3) 2 SnCl 3 , respectively. All compounds have been characterized by their IR spectra, two of them by X-ray diffraction studies. Ph — C(NSiMei) 2 AlCl 2 : Space group C2/c, Z = 4, 1152 independent observed reflexions, R = 0.052. Lattice dimensions (19 °C): a = 1558.6(1), b = 1116.6(1), c = 1307.0(1) pm, ß = 115.17(1)°. The compound forms monomeric molecules, in which the aluminium atom is tetra-hedrally coordinated by two chlorine atoms and by the two nitrogen atoms of the benzamidinato chelate. Bond length A1N = 188.2 pm. Ph — C(NSiMe^) 2 SnCU: Space group PI, Z = 2, 3293 independent observed reflexions, R = 0.034. Lattice dimensions (19 °C): a = 980.1(1), b = 1025.9(1), c = 1230.5(2) pm. a = 68.40(1)°, ß = 87.71(1)°, y — 68.92(1)°. The compound forms monomeric molecules, in which the tin atom is five-coordinated by three chlorine atoms and by the two nitrogen atoms of the benzamidinato chelate. Bond lengths SnN = 213.5 and 215.2 pm.
	Reference	Z. Naturforsch. 43b, 1621—1627 (1988); eingegangen am 18. August 1988
	Published	1988
	Keywords	N, N'Bis-(trimethylsilyl)amidinato Complexes, Synthesis, IR Spectra Crystal Structure
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	TEI-XML for	default:Reihe_B/43/ZNB-1988-43b-1621.pdf
	Identifier	ZNB-1988-43b-1621
	Volume	43

5	Author	CliffordW. Fonga, HamishG. Grant	Requires cookie*
	Title	Solvent Effects on the Carbon - 13 NMR Chemical Shifts and Rotational Barriers of N,N-Dimethylbenzamide - Solvent Enhanced n Polarization
	Abstract	The 13 C NMR chemical shifts of N,N-dimethylbenzamide in thirty solvents have been measured at high dilution. The solvent induced chemical shifts (s.i.c.s.) of the carbonyl group carbon atom in twenty three solvents and the thermodynamic barriers to rotation about the C-N bond in eleven solvents are linearly related to the solvent parameter, ET(30). Multi-parametric analysis of the carbonyl s.i.c.s. indicates hydrogen bond donor effects are more important than polar effects. Rotational barriers for N,N-dimethylbenz-amide may be determined by measurement of the 13 C chemical shift of the carbonyl group in a particular solvent. The s.i.c.s. of the aromatic ring carbon atoms may be explained by the polarization of the aromatic ji electron system induced by the solvent enhanced polarization of the dimethylcarboxamido moiety. Hydrogen bonding solvents and polar solvents result in two effective dipoles on the dimethylcarboxamido moiety, which polarize the aromatic n electron system differently.
	Reference	Z. Naturforsch. 36b, 585—595 (1981); received May 19 1980/January 21 1981
	Published	1981
	Keywords	Solvent Effects, 13 C NMR Spectra Rotational Barriers, N, N-Dimethylbenzamide
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	TEI-XML for	default:Reihe_B/36/ZNB-1981-36b-0585.pdf
	Identifier	ZNB-1981-36b-0585
	Volume	36

6	Author	;.M = Ti, ZrDieter Fenske, Eva Hartmann, Kurt Dehnicke	Requires cookie*
	Title	N,N'-Bis(trimethylsilyl)benzamidinato-Koniplexe von Titan und Zirkon. Die Kristallstrukturen von [C 6 H 5 -C(NSiMe3) 2 MCl 3 ] 2 ; M = Ti, Zr N,N'-Bis(trimethylsilyl)benzamidinato Complexes of Titanium and Zirconium. The Crystal Structures of [C 6 H 5 -C(NSiMe 3 ) 2 MCl 3 ]
	Abstract	The N,N'-bis(trimethylsilyl)benzamidinato complexes [C 6 H 5 -C(NSiMe 3) 2 MCl 3 ] 2 (M = Ti. Zr) have been prepared by the reactions of N,N,N'-tris(trimethylsilyl)benzamidine, [C 6 H 5 — C(NSiMe 3)N(SiMe 3) 2 ] with titanium tetrachloride, and zirconium tetrachloride, respec-tively. The compounds form moisture sensitive, dark red (Ti) and white (Zr) crystals, which were characterized by crystal structure determinations. [C 6 H 5 —C(NSiMe 3) 2 TiCl 3 ] 2 : space group P2,/rc. Z = 2, 4373 observed independent reflexions, R = 0.034. Lattice dimensions (-90 °C): a — 959.0(8); b = 1196.5(8); c = 1770.9(11) pm; ß = 93.79(4)°. [C 6 H 5 -C(NSiMe 3) 2 ZrCl 3 ] 2 : space group P2,/«. Z = 2, 3160 observed independent reflexions, R = 0.031. Lattice dimensions (-90 °C): a = 971.6(7); b = 1222.2(9); c = 1792.9(10) pm; ß = 93.51(5)°. Both complexes crystallize isotypically, forming centrosymmetric dimeric molecules via chloro bridges with bond lengths of 242.0 and 253.8 pm (Ti), and of 253.7 and 264.9 pm (Zr). The metal atoms complete their distorted octahedral surroundings with two chlorine ligands and the nitrogen atoms of the chelating amidinato ligand. The N atoms of the amidinato group are in equatorial and axial positions. This accounts for the different metal-nitrogen bond lengths of 207 pm (ax) and 199 pm (eq) in the titanium compound and 219 pm (ax) and 214 pm (eq) in the zirconium complex.
	Reference	Z. Naturforsch. 43b, 1611—1615 (1988); eingegangen am 22. Juni 1988
	Published	1988
	Keywords	N, N'-Bis(trimethylsilyl)benzamidinato Complexes, Titanium, Zirconium, Syntheses, IR Spectra
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	TEI-XML for	default:Reihe_B/43/ZNB-1988-43b-1611.pdf
	Identifier	ZNB-1988-43b-1611
	Volume	43

7	Author	Jan-K Arel Buijink, M. Athias, Noltemeyer Und, FrankT. Edelmann	Requires cookie*
	Title	Metall-N,N
	Abstract	-bis(trimethylsilyl)benzamidinate: Synthese und Kristallstruktur von Bis[N,N-bis(trimethylsilyl)benzamidinato)chroni(II), [P hC (N SiM e3)2l2Cr Metal-N,N'-bis(trimethylsilyl)benzamidinates: Synthesis and Crystal Structure of Bis[N,N'-bis(trimethylsilyl)benzamidinato]chromium(II), [PhC(NSiM e3)2]2Cr The preparation o f N,N'-bis(trimethylsilyl)benzamidinates o f chromium, manganese, zinc and bismuth is described. The chromium(II) derivative [PhC(NSiM e3)2]2Cr (2) has been char acterized by an X-ray structure determination. Treatment o f CpTiCl3 with one equivalent o f N a[PhC (N SiM e3),] • 0.5 Et^O yields the mixed Cp/benzamidinate complex [PhC(NSiM e3)2]CpTiCl2 (9).
	Reference	Z. Naturforsch. 46b, 1328—1332 (1991); eingegangen am 26. April 1991
	Published	1991
	Keywords	N, N'-Bis(trim ethylsilyl)benzam idinates, Chromium, Manganese, Zinc, Bismuth
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	TEI-XML for	default:Reihe_B/46/ZNB-1991-46b-1328.pdf
	Identifier	ZNB-1991-46b-1328
	Volume	46

8	Author	Fausto Calderazzo, Guido Pam, M. Artin Sperrlea, Ulli Englertb	Requires cookie*
	Title	Electron-and Ligand-Transfer Reactions Involving N,N-Dialkylcarbamates. Synthesis and Molecular Structure of V jIf^ -C C sH ^ yC ^ C N t^ H ^ h
	Abstract	Electron-and ligand-transfer reactions o f low-valent organom etallic com pounds o f titanium and vanadium with N,N-dialkylcarbam ates o f titanium(IV) are reported. The reaction o f VCp2 (Cp = ^-cyclopentadienyl) with T i(0 2C N E t2)4 affords, inter alia, the dimeric vana-dium(III) N ,N-diethylcarbam ato derivative V2Cp2(0 2C N E t2)4 which has been studied by X-ray diffraction methods. Crystal data; triclinic, space group P i; a = 10.802(2), b = 11.004(1), c = 8.960(1) Ä; a = 112.879(9), ß = 102.66(1), y = 102.42(1)°; V = 902.3(6) A 3; Z = 1; F(000) = 368, gcalc = 1.282 g em -3; n = 5.47 cm -1. It consists o f a centrosymmetric dimer, the two vanadium atom s being surrounded by four oxygen atom s o f the bridging N,N-diethylcar-bamato groups and by the cyclopentadienyl ligand. The metal atom exhibits a distorted square-pyramidal coordination geometry with the oxygen atom s occupying the basal plane. The reaction o f TiCp2(CO)2 or Vmes2 (mes = //6-l,3 ,5 -M e3C6H 3) with T i(0 2C N E t2)4 affords Ti(III) and V(III) N,N-diethylcarbam ato derivatives by a simultaneous ligand-and electron-transfer reaction. M agnesium N ,N-diisopropylcarbam ate, M g (0 2CNPr'2)2, has been obtained by a ligand-transfer reaction between M gCp2 and T i(0 2CNPr'2)3.
	Reference	Z. Naturforsch. 47b, 389 (1992); received A ugust 9 / October 16 1991
	Published	1992
	Keywords	N, N-D ialkylcarbam ates, Vanadium, Titanium, Cyclopentadienyl, Electron Transfer
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	TEI-XML for	default:Reihe_B/47/ZNB-1992-47b-0389.pdf
	Identifier	ZNB-1992-47b-0389
	Volume	47

9	Author	H. Möhrle, J. Mehrens	Requires cookie*
	Title	Reaktivität nitrophenylsubstituierter cyclischer Amine bei Dehydrierungen The Reactivity of Nitrophenyl Substituted Cyclic Amines with Dehydrogenations
	Abstract	Piperidine and perhydroazepine bearing a 1 -(4-nitrophenyl) substituent were inert to mercury-edta, while the a-pipecoline derivative gave an aminoketone with cleavage of the heterocycle. However the corresponding (2-nitrophenyl) compounds reacted to give respectively a piperidin-2-one, an aminopentanal and an aminohexanone. By an additional substituent in 2'-position the p-nitro compounds underwent dehydrogenation too. With a methyl group resulted a pattern analogous to o-nitro products. A neighbouring hydroxymethyl function enhanced the reaction with formation of benzoxazines and if possible their further oxidized derivatives, the hydroxylactams.
	Reference	(Z. Naturforsch. 53b, 37 [1998]; eingegangen am 8. Oktober 1997)
	Published	1998
	Keywords	Lactam, Iminium Salt, Aminoketone, N, 0-Acetal, Neighbour Group
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-0037.pdf
	Identifier	ZNB-1998-53b-0037
	Volume	53

10	Author	Kenji Nomiya, Nahoko Wako, Tomoko Komiyama, Makoto Miwa	Requires cookie*
	Title	Catalytic Oxygenation of 3-Methylindole by Co(II)-Schiff Base Planar Complexes
	Reference	Z. Naturforsch. 34b, 442—447 (1979); received November 13 1978
	Published	1979
	Keywords	Catalytic Oxygenation, 3-Methylindole, N, N'-Ethylenebis(acetylacetoniminato)Co(II), Manometric Observation, X H NMR
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	TEI-XML for	default:Reihe_B/34/ZNB-1979-34b-0442.pdf
	Identifier	ZNB-1979-34b-0442
	Volume	34

11	Author	Walter Dannecker, HansWerner Müller	Requires cookie*
	Title	Ureadiid-Derivate von Mangan(I)-und Rhemum(I)-carbonylen Ureadiide Derivatives of Manganese (I) and Rhenium (I) Car bony Is
	Reference	Z. Naturforsch. 37b, 318—323 (1982); eingegangen am 3. November 1981
	Published	1982
	Keywords	N, N'-Diorganyl-ureadiides, Monodentate Ligand (N-Coordination), Bidentate Ligand (N, 0-Coordination)
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	TEI-XML for	default:Reihe_B/37/ZNB-1982-37b-0318.pdf
	Identifier	ZNB-1982-37b-0318
	Volume	37

12	Author	Evamarie Hey, Christina Ergezinger, Kurt Dehnicke	Requires cookie*
	Title	Die Reaktion von N
	Abstract	,N,N'-Tris(trimethylsilyI)benzamidin mit Kupfer(II)chlorid. Kristallstruktur von {C 6 H 5 -C(NSiMe 3) 2 CuCl [C 6 H 5 -C(NSiMe 3)(NHSiMe 3)]} The Reaction of N,N,N'-Tris(trimethylsilyl)benzamidine with Copper(II) Chloride. Crystal Structure of {C 6 H 5 —C(NSiMe 3)->CuCl • [C 6 H 5 -C(NSiMe 3)(NHSiMe 3)]}
	Reference	Z. Naturforsch. 43b, 1679—1682 (1988); eingegangen am 27. Juni 1988
	Published	1988
	Keywords	N, N'-Bis(trimethylsilyl)benzamidinato-copper Chloride-N, N'-bis(trimethylsilyl)benzamidine Adduct, Synthesis, IR Spectrum, Crystal Structure
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	TEI-XML for	default:Reihe_B/43/ZNB-1988-43b-1679_n.pdf
	Identifier	ZNB-1988-43b-1679_n
	Volume	43

13	Author	JohnDavid Kildea, Wolfgang Hiller, Beatrice Borgsen, Kurt Dehnicke	Requires cookie*
	Title	Synthese, IR-Spektrum und Kristallstruktur des Amidinatokomplexes [N a(15-K rone-5)][Ph—C(NSiM e3)2SnCl3F] Synthesis, IR Spectrum, and Crystal Structure of the Amidinato Complex [N a(15-Crow n-5)][Ph-C(N SiM e3)2SnCl3F]
	Reference	Z. Naturforsch. 44b, 889 (1989); eingegangen am 30. März 1989
	Published	1989
	Keywords	N, N '-Bis(trim ethylsilyl)am idinato C om plex, Synthesis, IR Spectra, Crystal Structure
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	TEI-XML for	default:Reihe_B/44/ZNB-1989-44b-0889.pdf
	Identifier	ZNB-1989-44b-0889
	Volume	44

14	Author	H. Möhrle, M. Jeandrée	Requires cookie*
	Title	,3-Dioxolane von N-substituierten 4-Piperidonen als Dehydrierungssubstrat 1,3-Dioxolanes of N-Substituted 4-Piperidones as Substrates for Dehydrogenations
	Abstract	The applicability of ketals was examined for masking the carbonyl group in N-tertiary 4-piperidones during the dehydrogenation using mercury-edta. Various 1,3-dioxolanes showed a different behaviour in dependence on the N-substituent. With simple aliphatic moieties mainly dehydrogenated but hydrolyzed products were received. These enaminones were also available from the dehydrogenations of the corresponding 4-piperidones. Similar applied to para-acyl-aromatic substituted derivatives but with less yields. Aromatic substituents bearing a neighbour group on ortho-position with participation gave rise to different oxidation products partially with preservation of the ketal structure.
	Reference	(Z. Naturforsch. 52b, 72—78 [1997]; eingegangen am 23. August 1996)
	Published	1997
	Keywords	Ketals, Enaminones, N, 0-A cetals, Lactams, Dehydrogenation with Hg-EDTA Complex
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	TEI-XML for	default:Reihe_B/52/ZNB-1997-52b-0072.pdf
	Identifier	ZNB-1997-52b-0072
	Volume	52

15	Author	Andreas Böhm, Kurt Polborn, Karlheinz Sünkel, Wolfgang Beck	Requires cookie*
	Title	Metallkomplexe mit biologisch wichtigen Liganden, CIV [1]. or/Zio-Palladierte Komplexe von N,N-DimethyI-C-phenyl-glycinmethylester. Synthese von a-Aminosäure-Derivaten durch Insertion von Isocyaniden, CO, Alkenen und Alkinen in die Pd-C-Bindung Metal Complexes of Biologically Important Ligands, CIV [ 1]. o/t/20-Palladated Complexes of N,N-Dimethyl-C-phenylglycine-methylester. Synthesis of ct-Amino Acid Derivatives by Insertion of Isocyanides, CO, Alkenes, and Alkynes into the Pd-C Bond
	Abstract	-phenylglycinemethylester reacts with Pd(OAc)2 in acetic acid to give the orthopalladated, acetato bridged complex 1. Treatment of 1 with sodium halide affords the chlo-ro, bromo, and iodo bridged compounds [Me2N C (H)(C 02Me)C6H4PdX]2 (2a -c) (X = halide). From 2a and 1,1 '-bis(diphenylphosphino)ferrocene the phosphine bridged trinuclear complex 3 is obtained. Substitution of the amine ligand of 2a by the phosphino group is observed for the reaction of 2a with Ph2PC(Me)C(Me)PPh2. Insertion of 2,6-dimethyl-phenylisocyanide, CO, alkyl-vinyl-ketones, and diphenylacetylene into the Pd-C bond o f 2a -c provides the ortho substituted organic and organometallic derivatives of phenylglycine 6a -c, 7, 8a -b and 9a -c. The crystal structures of 1, 4a, 6a, 7 and 9a were determined by X-ray diffraction.
	Reference	Z. Naturforsch. 53b, 448—458 (1998); eingegangen am 19. Dezember 1997
	Published	1998
	Keywords	Palladium(II) Complexes, ortho-Palladation, N, N-Dimethyl-C-phenylglycine, Insertion Reactions N, N-Dimethyl-C
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-0448.pdf
	Identifier	ZNB-1998-53b-0448
	Volume	53

16	Author	Jones	Requires cookie*
	Title	Polysulfonylamine, CV [1] Die ersten N,N-disulfonylierten Sulfinsäureamide: Synthese und Kristallstrukturen von R S ( 0 )-N (S 0 2Me)2 (R = Me, CC13)
	Abstract	P o ly su lfo n y lam in es, C V [1] T h e F irst N ,N -D isu lfo n y lated S ulfinic A m id es: S y nthesis a n d C ry sta l S tru c tu re s o f R S (0) -N (S 0 2M e)2 (R = M e, CC13) M a rtin a N äv e k e, A rm a n d B lasc h ette* , P e te r G. The novel sulfinamides R S (0) -N (S 0 2M e)2, where R = Me (la) or CC13 (lb), were ob tained by treating the corresponding sulfinyl chlorides with Me3S iN (S 02Me)2 or AgN-(S 0 2Me)2, respectively. A presumedly ionic 1:1 adduct of lb with 4-dimethylaminopyridine was isolated and analytically characterized. In the crystals of la (monoclinic, space group P2\!ri) and lb (monoclinic, P l j c) , the molecules feature approximately planar NS3 moieties, unusually long S (0) -N bonds and, in the case of lb, an extremely long S (0) -C bond [for la and lb, in order: sum of bond angles at nitrogen 359.5 and 357.1°, S (0) -N 178.2(2) and 173.6(2) pm, S (0) -C 178.8(2) and 194.1(2) pm]. In both molecular structures, an attractive S (0) --0 1,4-interaction leads to a 7.3° discrepancy in the S (0) -N -S 0 2 angles. The crystal packing of la displays a tape (double-chain) motif generated by two prominent intermolecu-lar C -H -O interactions involving one M e S 0 2 group and the sulfinyl oxygen atoms of two adjacent molecules, whereas in lb the molecules are associated into parallel chains via a bonding C l-"0(sulfonyl) interaction.
	Reference	Z. Naturforsch. 53b, 734—741 (1998); eingegangen am 6. April 1998
	Published	1998
	Keywords	N, N-Bis(organosulfonyl)sulfinamides, Synthesis, Crystal Structure, Long S ( 0 ) -N Bond
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-0734.pdf
	Identifier	ZNB-1998-53b-0734
	Volume	53

17	Author	Hans Bock, N. Orbert, N. Agel, C. Hristian, N. Äther	Requires cookie*
	Title	Wechselwirkungen in Molekülkristallen, 147 [1, 2 ]. Isostrukturelle Wirt/Gast-Einschluß-Verbindungen von N,N'-Ditosyl- p-phenylendiamin mit Aceton, Cyclopentanon, Cyclopent-2-en-l-on, 1,3-Dioxolan, Tetrahydrofuran und 2,5-Dihydrofuran
	Abstract	Interactions in M olecular Crystals, 147 [1, 2], Isostructural H ost/G uest-Inclusion Com pounds o f N ,N'-D itosyl-/?-phenylenediam ine w ith A cetone, C yclopentanone, C yclopent-2-ene-l-one, 1,3-Dioxolane, Tetrahydro furane, and 2,5-D ihydrofurane H errn P ro fe sso r M a n fre d E igen g e w id m e t
	Reference	Z. Naturforsch. 53b, 1401—1412 (1998); eingegangen am 19. August 1998
	Published	1998
	Keywords	N, N'-Ditosyl-p-phenylenediamine, Inclusion Compounds, Crystal Growth, Structures, Host/Guest-Relations
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-1401.pdf
	Identifier	ZNB-1998-53b-1401
	Volume	53

18	Author	Hans Bock, N. Orbert, N. Agel, C. Hristian, N. Äther	Requires cookie*
	Title	Wechselwirkungen in Molekülkristallen, 149 [1 -3]. Wirt/Gast-Einschlußverbindungen von NjN'-Ditosyl-p-phenylendiamin: Die Wasserstoffbrücken-Addukte mit Morpholin; Pyridin, N,N-Dimethylformamid und Dimethylsulfoxid
	Abstract	Interactions in M olecular C rystals, 149 [1 -3]. H ost/G uest-Inclusion Com pounds of N ,N'-D itosyl-/?-phenylenediam ine: The H ydrogen Bonded Adducts with M orpholine, Pyridine, N ,N -D im ethylform am ide, and D im ethylsulfoxide H errn P ro fe sso r M a n fred E igen g e w id m e t
	Reference	Z. Naturforsch. 53b, 1425—1439 (1998); eingegangen am 19. August 1998
	Published	1998
	Keywords	N, N'-Ditosyl-/?-phenylenediamine, Inclusion Compounds, Hydrogen Acceptor and Donor Guest Molecules, Crystal Growth, Structures
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-1425.pdf
	Identifier	ZNB-1998-53b-1425
	Volume	53

19	Author	Andreas Böhm, Kurt Polborn, Wolfgang Beck	Requires cookie*
	Title	Metal Complexes of Biologically Important Ligands, CX [1]. Orthopalladation of N-(Diphenylmethylene) Schiff Bases from Peptide Esters -C,N versus C,N,0 Coordination -Crystal Structure of ClPd[C6H4(C6H5)C=N(Gly-L-Pr0-L-Ala-OMe)-C,N,O] with cis/trans Peptide Bonds
	Abstract	The reaction of the N-(diphenylmethylene) Schiff base from glycyl-L-prolyl-L-alanine methyl ester 1 with tetrachloropalladate in the presence of sodium acetate affords the or-thopalladated bicyclic C ,N ,0 chelate 2. Complex 2 was characterized by X-ray diffraction. Remarkably, the unit cell contains two independent molecules, the cis isomer 2a and the trans
	Reference	Z. Naturforsch. 54b, 300—304 (1999); received October 10 1998
	Published	1999
	Keywords	N-(Diphenylmethylene) Peptide Esters, Orthopalladation, C, N, 0 Chelate, cis/trans Peptide Bonds
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	TEI-XML for	default:Reihe_B/54/ZNB-1999-54b-0300.pdf
	Identifier	ZNB-1999-54b-0300
	Volume	54

20	Author	Hans Bock, Norbert Nagel, Peter Eller, Herrn Professor, Manfred Eigen	Requires cookie*
	Title	Wechselwirkungen in Molekülkristallen, 153 [1 -3]. Wirt/Gast-Einschlußverbindungen von N,Nf-Ditosyl-/?-phenylendiamin- Derivaten: Die Kristallstrukturen von N,N'-Di(4-ethyl-benzosulfuryl)-/?- phenylendiamin und seinen Aggregaten mit Aceton und Cyclopentanon Interactions in Molecular Crystals, 153 [1 -3]. Host/Guest-Inclusion Compounds of N,N'-Ditosyl-/?-phenylenediamine Derivatives: The Crystal Structures o f N,N'-Di(4-ethyl- benzosulfuryl)-/?-phenylenediamine and its Aggregates with Acetone and Cyclopentanone
	Reference	Z. Naturforsch. 54b, 491—500 (1999); eingegangen am 26. Oktober 1998
	Published	1999
	Keywords	N, N'-Di(4-ethyl-benzosulfuryl)-p-phenylenediamine, Inclusion Compounds, Ketone Guest Molecules, Crystal Growth, Structures
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	TEI-XML for	default:Reihe_B/54/ZNB-1999-54b-0491.pdf
	Identifier	ZNB-1999-54b-0491
	Volume	54

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