| | 1 | Author
| Karl Hensen3, Frank Gebhardta, Michael Bolteb | Requires cookie* | | | Title
| Synthese und Kristallstrukturbestimmung von Additionsverbindungen aus Alkyldimethylbromsilanen und N-Trimethylsilylimidazol Syntheses and Crystal Structure Determination of Addition Compounds of Alkyldimethylbromosilanes and N-Trimethylsilylimidazole  | | | | Abstract
| The bromosilanes RMe2SiBr (R = Me, Et, n-Pr and /-Pr) form ionic l:l-compounds with N-trimethylsilylimidazole (NTMSI), stable at room temperature. Crystals of the compounds with R = Et, n-Pr and i-Pr are obtained by sublimation. From the product of the reaction of 1,1-dibromosilacyclopentane with NTMSI single crystals of N,N'-bis(trimethylsilyl)imidazolium-bromide (R = Me) were obtained. In the new adducts both silicon atoms are tetracoordinated. | | | |
Reference
| Z. Naturforsch. 52b, 1491—1496 (1997); eingegangen am 31. Juli 1997 | | | |
Published
| 1997 | | | |
Keywords
| Alkyldimethylbromosilanes (alkyl = Me, Et, «-Pr and /-Pr), N-Trimethylsilylimidazole, Lewis-Acid-Base Adducts, Crystal Structure | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/52/ZNB-1997-52b-1491.pdf | | | | Identifier
| ZNB-1997-52b-1491 | | | | Volume
| 52 | |
|
