| | 1 | Author
| Regina Bettenhausen, Wolfgang Milius, Wolfgang Schnick | Requires cookie* | | | Title
| Synthese und Kristallstruktur von [H2NMe2]+[(Me2 NH)2 TiCl4 ]_ Synthesis and Crystal Structure of [H2NMe2]+[(Me2NH)2TiCl4]~  | | | | Abstract
| The title compound has been synthesized as a green solid by the reaction of M eCl2 SiNHSiM e3 and Ti(NM e2)4 in CH2C12. The crystal structure was determined by single crystal X-ray methods at room temperature (C2/c, a = 1825,7(4), b = 909,9(2), c = 1116,1(2) pm, ß = 125,09(3)°, Z = A,R\= 0,047, wR2 = 0,147) to be an ionic salt [H2NMe2]+[(Me2NH)2TiCl4]" . The central titanium(III) atom of the anion is bound to four Cl atoms and weakly coordinated by two Me2NH ligands. | | | |
Reference
| Z. Naturforsch. 53b, 239—241 (1998); eingegangen am 20. November 1997 | | | |
Published
| 1998 | | | |
Keywords
| N-Silyl Amides, Crystal Structure, Titanium | | | |
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| default:Reihe_B/53/ZNB-1998-53b-0239.pdf | | | | Identifier
| ZNB-1998-53b-0239 | | | | Volume
| 53 | |
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