| 1 | Author
| Fritz Seel, Norbert Klein | Requires cookie* | | Title
| N-Methylcarbamoylphosphate, I. Synthese N-Methylcarbamoyl Phosphates, I. Synthesis  | | | Abstract
| Solutions of mono-and bis-N-methylcarbamoyl phosphates in non-aqueous solvents [e.g. acetonitrile, dimethyl formamide, chloroform) and, surprisingly, even in water are readily obtained by the reaction of methyl isocyanate with the solution of an appropriate mono-or dihydrogenphosphate. The course of the reactions and the limited stability of N-methylcarbamoyl phosphate ions in solutions can be monitored through 31 P NMR measurements. Various types of compounds, including a coordination compound of cobalt could.be isolated in crystalline form: [Et3NH]HX, KHX, NH4HX, Na2X • H20, MgX • 4 H20, CaX • H20, SrX • 2 HaO, BaX • H20, ZnX • 5 H20, CdX • 2 H20, [(NH3)5COX]C104, [EtsNHjY, AgY • MeCN, X = MeNHC(0)0P03, Y = [MeNHC(0) 0]2P02. | | |
Reference
| Z. Naturforsch. 38b, 797—803 (1983); eingegangen am 24. Februar 1983 | | |
Published
| 1983 | | |
Keywords
| N-Methylcarbamoyl Phosphates, Preparation, NMR Spectra | | |
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| default:Reihe_B/38/ZNB-1983-38b-0797.pdf | | | Identifier
| ZNB-1983-38b-0797 | | | Volume
| 38 | |
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