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1979 (1)
1Author    Volker Küllmer, Erika Röttinger, Heinrich VahrenkampRequires cookie*
 Title    Phosphinsubstituierte Carbonyl-Seleno-Komplexe des Mangans und Rheniums Phosphine Substituted Carbonyl Seleno Complexes of Manganese and Rhenium  
 Abstract    The selenium bridged complexes [(CO)4M-SeX]2 (M = Mn, Re; X = H, SnMe3) were converted by trimethylphosphine to the dimers [Me3P(CO)3M-SeX]2 and/or the monomers (Me3P)2(CO)3M-SeX. The obtained Se-SnMe3 compounds reacted with HCl to form the SeH compounds. The structures of the new complexes were deduced from their IR and NMR spectra. [(Me3P)2(CO)3Re]2Se, the first monobridged bis-earbonylmetal chalcogenide, was obtained as a byproduct and confirmed by a crystal structure analysis. Die metallorganischen Lewis-Basen des Typs 
  Reference    Z. Naturforsch. 34b, 217—223 (1979); eingegangen am 29. September 1978 
  Published    1979 
  Keywords    Dimeric Complexes, Monomerie Complexes, Crystal Structure, Carbonyl Seleno Complexes 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-0217.pdf 
 Identifier    ZNB-1979-34b-0217 
 Volume    34