| 1 | Author | Alena Novoselova, Vladimir Khokhlov, Vladimir Shishkin | Requires cookie* |
| Title | Thermodynamic Characteristics of Samarium and Europium Chlorides in Molten Alkali Metal Chlorides  | ||
| Abstract | The formal standard redox potentials of samarium (III)/(II) (EZmi+/ Smi+) and europium (III)/(II) (• £, £u3+/eu2+) *n molten alkali metal chlorides were measured potentiometrically against a reference chlorine electrode. The Gibbs energy changes and equilibrium constants for the reaction LnCl2(D + V2 Cl2(g) LnCl3(I) were calculated for the salt systems studied. The effect o f the cationic composition of the melt-solvent on the above thermodynamic characteristics is also reported. | ||
| Reference | Z. Naturforsch. 56a, 837—840 (2001); received August 20 2001 | ||
| Published | 2001 | ||
| Keywords | Thermodynamic Stability, Rare Earth Chlorides, Molten Alkali Metal Chlorides, Redox Potentials, Gibbs Energy Changes | ||
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