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2001 (1)
1Author    Alena Novoselova, Vladimir Khokhlov, Vladimir ShishkinRequires cookie*
 Title    Thermodynamic Characteristics of Samarium and Europium Chlorides in Molten Alkali Metal Chlorides  
 Abstract    The formal standard redox potentials of samarium (III)/(II) (EZmi+/ Smi+) and europium (III)/(II) (• £, £u3+/eu2+) *n molten alkali metal chlorides were measured potentiometrically against a reference chlorine electrode. The Gibbs energy changes and equilibrium constants for the reaction LnCl2(D + V2 Cl2(g) LnCl3(I) were calculated for the salt systems studied. The effect o f the cationic composition of the melt-solvent on the above thermodynamic characteristics is also reported. 
  Reference    Z. Naturforsch. 56a, 837—840 (2001); received August 20 2001 
  Published    2001 
  Keywords    Thermodynamic Stability, Rare Earth Chlorides, Molten Alkali Metal Chlorides, Redox Potentials, Gibbs Energy Changes 
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 TEI-XML for    default:Reihe_A/56/ZNA-2001-56a-0837.pdf 
 Identifier    ZNA-2001-56a-0837 
 Volume    56