| 1 | Author | Hiroyuki Ishida, Naoki Kumagae, Setsuko Satoa | Requires cookie* |
| Title | Motions of Ethylammonium Ions in Solid Ethylammonium Chloranilate Studied by 1H Nuclear Magnetic Resonance  | ||
| Abstract | The motions of the ethylammonium ion in solid ethylammonium chloranilate, C2H5NH3 • Q H O 4CI2, are studied by *H NMR second moment (M2) and spin-lattice relaxation time {Tx) measurements. Re orientations of the CH3 group about the C-C bond axis and the NH3 group about C -N bond axis were observed and their motional parameters were evaluated. The internal rotational barriers of the CH3 and NH3 groups of an isolated C2H5NH3 ion were estimated from ab initio molecular orbital calculations. | ||
| Reference | Z. Naturforsch. 56a, 523 (2001); received April 30 2001 | ||
| Published | 2001 | ||
| Keywords | Nuclear Magnetic Resonance, Molecular Motion, Ethylammonium Ion, HF | ||
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