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1Author    Hans-Georg Von Schnering, Wolfgang MayRequires cookie*
 Title    Die Struktur des 2  
 Abstract    One of the diastereomeres of 2,3,4,6,7,8-hexamethyl-2,3,4,6,7,8-hexaphosphabicyclo-[3,3,0]octane (PMe)öC2H2 crystallizes in the space group P2i/n with four molecules per unit cell. Two independent molecules are nearly identical in shape but differ by inter-molecular packing. The five-membered rings have a skew chair conformation with all exocyclic methyl groups in axial positions leading to a staggered all-trans conformation of the bicyclic system. The mean bond lengths are P-P = 220.9 pm, P-C = 185.9 pm and C-C = 151.9 pm. 
  Reference    Z. Naturforsch. 33b, 698—698 (1978); eingegangen am 24. April 1978 
  Published    1978 
  Keywords    Carbaphosphane, Molecular Structure, Crystal Structure 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0698.pdf 
 Identifier    ZNB-1978-33b-0698 
 Volume    33 
2Author    G. Struckmeier, J. Engel, U. ThewaltRequires cookie*
 Title    Molekül-und Kristallstruktur des 5.5' -Diethoxycarbonyl-3.3' -diethyl-4.4' -dimethyl-pyrromethen-hydrobromids Crystal and Molecular Structure of 5,5'-Diethoxycarbonyl-3,3'-chethyl-4,4'-cÜmethyl-pyiTomethene Hydrobromide  
 Abstract    The crystal and molecular structure of the title compound has been determined by X-ray diffraction. The compound possesses an (almost) planar Z configuration. The ions form ion pairs in the solid state: each bromide anion is connected via two hydrogen bonds with a cation. The crystal data are: space group P2i/n with Z = 4; cell dimensions a = 14.097(2), b = 11.591(2), c = 14.133(3) A, ß = 106,22(2)°. 
  Reference    Z. Naturforsch. 33b, 753—755 (1978); eingegangen am 12. April 1978 
  Published    1978 
  Keywords    Pyrromethenes, X-ray, Molecular Structure 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0753.pdf 
 Identifier    ZNB-1978-33b-0753 
 Volume    33 
3Author    Dirk Dahmann, Hans Rose, Wolfgang WalzRequires cookie*
 Title    Darstellung und Struktur von Phosphazenylcyclophosphazenen Synthesis and Structure of Phosphazenylcyclophosphazenes  
 Abstract    Various phosphazenylcyclophosphazenes N3P3Xn(N = PA3)e-n with X = Cl, F, A = Me, Ph, NMe2, OEt, OPr», OBut" and n = 1-3 were obtained by desilylation methods. Chemical and spectroscopical properties dependent on the substituents are discussed. Isomers of di-and tri-substituted compounds were isolated and their structures elucidated by NMR spectroscopy. 
  Reference    Z. Naturforsch. 35b, 964—969 (1980); eingegangen am 14. Dezember 1979 
  Published    1980 
  Keywords    Phosphazenylcyclophosphazenes, Molecular Structure, Synthesis 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0964.pdf 
 Identifier    ZNB-1980-35b-0964 
 Volume    35 
4Author    Cyclic Diazastannylenes, Iii, M. VeithRequires cookie*
 Title    Cyclische Diazastannylene, DI 1 Die Kristall-und Molekülstruktur der monoklinen Phase von 1.3-Di-feri-butyl-2.2-dimethyl- 2 -diazasilastannetidin The Crystal and Molecular Structure of the Monoclinic Phase of l,3-Di-feri-butyl-2,2-dimethyl-l,3,2,4A 2 -diazasilastannetidine  
 Abstract    The crystal and molecular structure of the monoclinic phase of l,3-di-£eri-butyl-2,2-dimethyl-l,3,2,4A 2 -diazasilastannetidine has been determined from three-dimensional X-ray data collected on a two-circle diffractometer at —120 °C (MoKa radiation, 2623 re-flexions, R — 0,050). The crystals are monoclinic, space group C 2/c, with cell dimensions a = 10.655(5), b = 25.75(1), c = 17.33(1) A, ß = 106.8(1)° and Z = 12. Four monomeric (crystal site symmetry 2 (C2)) and four dimeric units (crystal site symmetry I (Cj)) are present in the structure interacting over tin-tin (3.68 A). Remarkable are the very short Sn-N bond (2.09 A) in the monomer and the donation bond Sn-N (2.39 Ä) in the dimer. The coordination of the tin atoms in the different units is discussed in detail. 
  Reference    (Z. Naturforsch. 33b, 7—13 [1978]; eingegangen am 5. September/6. Oktober 1977) 
  Published    1978 
  Keywords    Diazastannylenes, X-ray, Molecular Structure, Crystal Structure 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0007.pdf 
 Identifier    ZNB-1978-33b-0007 
 Volume    33 
5Author    A. Müller, N. Mohan, H. BöggeRequires cookie*
 Title    Molekül-und Elektronenstruktur des Thioheteroanions [S2 WS2CoS2WS2] 2 - Molecular and Electronic Structure of the Thiohetero Anion [S2WS2CoS2WS2] 2  
 Abstract    The crystal and molecular structure of [(C6H5)4P]2[Co(WS4)2] was determined from single crystal X-ray diffraction data (space group P2i/c with a = 18.542(4), b — 15.443(2), c= 18.713(2) A, /?= 108.73(1)°, Z = 4). In the complex anion Co is coordinated by two bidentate chelating WS4 2 -anions, with a nearly tetrahedral surrounding of Co. The bond lengths in the planar metal sulfur ring CoS2W are Co-S = 2.26 A and W-S = 2.22 A, while the terminal W-S bonds are 2.14 A. 
  Reference    Z. Naturforsch. 33b, 978—982 (1978); eingegangen am 8. Mai 1978 
  Published    1978 
  Keywords    Crystal Structure, Molecular Structure, Thiohetero Anion, Electronic Structure 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0978.pdf 
 Identifier    ZNB-1978-33b-0978 
 Volume    33 
6Author    H. J. Keller, R. Martin, U. TraegerRequires cookie*
 Title    Kristall-und Molekülstruktur eines  
 Abstract    "linearen 66 Festkörpers mit drei verschiedenen Metallsträngen: [Pt(dapn)2] [Pt(dapn)2Br2] [(Cu3Br5)2] (dapn = 1.2-Diaminopropan) Crystal and Molecular Structure of a Linear Chain Solid with Three Different Metal Chains: [Pt(dapn)2][Pt(dapn)2Br2][(Cu3Br5)2] (dapn = 1,2-diaminopropane) The compound {[Pt(dapn)2][Pt(dapn)2Br2]}(Cu3Br5)2, which was prepared by oxidation of Pt(dapn)2Br2 with CuBr2, crystallizes in the orthorhombic space group Bmmb (D^h), a = 5.617(4) A, b = 16.206(6) A, c = 22.00(1) A, Z = 2. The experimentally determined density is 3.22 g • cm -3 (calculated 3.40). The structure has been determined by Patterson and Fourier methods from single crystal diffractometer data and refined by least squares to R = 0.085 for 485 independent reflections. Crystals of the title compound contain halide-bridged copper and platinum chains. 
  Reference    Z. Naturforsch. 33b, 1263—1266 (1978); eingegangen am 14. Juli 1978 
  Published    1978 
  Keywords    Linear Chain Transition Metal Complexes, Crystal Structure, Molecular Structure 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-1263.pdf 
 Identifier    ZNB-1978-33b-1263 
 Volume    33 
7Author    M. VeithRequires cookie*
 Title    Cyclische Diazastannylene, VIII [1] Die Kristall-und Molekülstruktur eines Iminostannylens: Sn3 (NC(CH3 )3 )4 H2 Cyclic Diazastannylenes, VIII [1] The Crystal and Molecular Structure of an Iminostannylene: Sn3(NC(CH3)3)4H2  
 Abstract    The crystal and molecular structure of the compound Sn3(NC(CH3)3)4H2 has been determined from X-ray data (R = 0.044). The crystals are cubic, space group Pa3, with cell dimension a — 1713.6(8) pm and Z = 8. The molecules, which have a seco-norcubane like Sn3N4 framework, are statistically disordered, thus forming closed packed pairs of molecules. The Sn3N4 cage deviates strongly from a cube, the bond angles at Sn approach-ing 80°, and at N 100°. The averaged Sn-N bond distance is 223(1) pm. 
  Reference    (Z. Naturforsch. 35b, 20—24 [1980]; eingegangen am 3. September/8. Oktober 1979) 
  Published    1980 
  Keywords    Iminostannylenes, X-ray, Crystal Structure, Molecular Structure, Disorder 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0020.pdf 
 Identifier    ZNB-1980-35b-0020 
 Volume    35 
8Author    Hans-Friedrich Klein, Joachim Groß, Jean-Marie Bassett, Ulrich SchubertRequires cookie*
 Title    Semicobaltate -Alkalimetall-Träger in Kohlenwasserstoffen Darstellung, Eigenschaften und Struktur von K[Co(C2H4)(PMe3)3]2 Semicobaltates -Alkali Metal Carriers in Hydrocarbons Synthesis, Properties, and Structure of K[Co(C2H4)(PMe3)3]2  
 Abstract    Semicobaltates (Co-1/2) containing olefin and trimethylphosphane ligands are synthe-sized from Co(olefin)(PMe3)3 and potassium metal. The X-ray crystal structure determina-tion of the title compound shows that the unit cell contains two K atoms in equal ionic contact with the ethylene ligands of four Co(C2H4)(PMe3)3 complex units, two of which are interacting with both K atoms. In solution the semicobaltates exist in hydrocarbon solvents under argon only, while in contrast under ethylene or nitrogen atmospheres or in donor solvents disproportionation occurs to give Co(O) and Co(-I) species. Allgemeines 
  Reference    Z. Naturforsch. 35b, 614—619 (1980); eingegangen am 3. Januar 1980 
  Published    1980 
  Keywords    Potassium-Ethylene Semicobaltate, Synthesis, Molecular Structure, Crystal Structure 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0614.pdf 
 Identifier    ZNB-1980-35b-0614 
 Volume    35 
9Author    Rainer Mattes, Franz WaldmannRequires cookie*
 Title    Molekülstruktureii, Schwingungsspektren und Konformation der Thiooxalsäurederivate CH3S-CO-CONH2, CH3S-CS-CONH2, C2H50-C0-CSNH2 und K[OSC-CONH2] Molecular Structure, Vibrational Spectra and Conformation of the Thiooxalic Acid Derivatives CH3S-CO-CONH2, CH3S-CS-CONH2, C2H50-C0-CSNH2 and K[OSC-CONH2]  
 Abstract    The crystal structures ofCH3S-CO-CONH2 (1), CH3S-CS-CONH2 (2), C2H50-C0-CSNH2 (3) and K[OSC-CONH2] (4) have been determined by single crystal X-ray diffraction. The molecules 1, 2 and 3 are nearly planar and form centrosymmetric dimers by N H • • • O or N-H--S hydrogen bonds with the amidic oxygen or sulfur atom as acceptor atoms. The anion of 4 is not quite planar. The torsional angle around the C-C bond is 18.4°. The con-formations of the title compounds are E, Z' (1 and 2), Z, Z' (3) and Z (4). According to the vibrational spectra, which are discussed briefly, 1 and 3 retain their conformation also in solution. 
  Reference    Z. Naturforsch. 38b, 335—340 (1983); eingegangen am 5. November 1982 
  Published    1983 
  Keywords    Molecular Structure, Conformation, Vibrational Spectra, Thiooxalic Acid Derivatives 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0335.pdf 
 Identifier    ZNB-1983-38b-0335 
 Volume    38 
10Author    Achim Müller, Winfried Hellmann, Uwe Schimanski, Rainer Jostes, WilliamE. NewtonRequires cookie*
 Title    On the Central Role of Sulfur in Multi Metal Aggregates with Different Electron Populations: [S2WS2CoS2WS2]' 1 - (n -2, 3)  
 Abstract    The hetero metal sulfur aggregates [Co(WS4)2] n ~ (with variable electron popula-tion: n = 2, 3) could be isolated as salts and characterized by physical measurements (in-cluding X-ray structure analysis). Experimental and theoretical investigations show that due to a strong metal -> ligand electron delocalisation WS4 2-(like M0S4 2 -) is a non-innocent ligand and that the additional charge upon reduction is located mainly at the S atoms of the ligand system. 
  Reference    Z. Naturforsch. 38b, 528—529 (1983); eingegangen am 12. November 1982 
  Published    1983 
  Keywords    Preparation, Crystal Structure, Molecular Structure, Electronic Structure, Thioanions 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0528_n.pdf 
 Identifier    ZNB-1983-38b-0528_n 
 Volume    38 
11Author    Liv Fernholt, Arne Haaland, Ragnhild Seip, Rüdiger Kniep, Lutz KorteRequires cookie*
 Title    The Molecular Structure of Selenium Dichloride, SeCl2, Determined by Gas Electron Diffraction  
  Reference    Z. Naturforsch. 38b, 1072—1073 (1983); eingegangen am 19. Mai 1983 
  Published    1983 
  Keywords    Molecular Structure, Selenium(II) Chloride, Gas Electron Diffraction 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-1072.pdf 
 Identifier    ZNB-1983-38b-1072 
 Volume    38 
12Author    Otto Mündt, Heinz Riffel, Gerd Becker, Arndt SimonRequires cookie*
 Title    Element—Element-Bindungen, IV [1] Molekül-und Kristallstruktur des Tetramethyldiphosphans und -diarsans Element—Element Bonds, IV [1] Molecular and Crystal Structure of Tetramethyldiphosphane and -diarsane  
 Abstract    The molecular and crystal structures of the isotypic compounds tetramethyldiphosphane 1 and -diarsane 2 have been determined by single crystal X-ray diffraction (monoclinic; C2/m; Z = 2; 1/2: -155/-144 °C\a = 540.6(2)/555.8(2); b = 1131.0(6)/l 136.7(6); c -602.5(2)/612.8(2) pm;/? = 97.31(3)/95.24(3)°;P-P 221.2(1)/As-As 242.9(1) pm). In accordance with the crystallographically imposed symmetry 2/m, the molecules adopt antiperiplanar conformation. Their crystal structures are closely related to those of the homologues tetramethyldistibane 3 [1] and -dibismuthane 4 [3]. As found for the latter compounds, the E —E units (E = P, As) are also aligned in linear chains, but the intermolecular E---E contacts (P-P 381/As---As 370 pm) do not allow any extended interaction between molecules, which otherwise would result in thermochromic effects. 
  Reference    Z. Naturforsch. 43b, 952—958 (1988); eingegangen am 29. Februar 1988 
  Published    1988 
  Keywords    Tetramethyldiphosphane, Tetramethyldiarsane, Conformation, Molecular Structure, Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0952.pdf 
 Identifier    ZNB-1988-43b-0952 
 Volume    43 
13Author    U. Lf Thewalt, Thomas WöhrleRequires cookie*
 Title    Titanium(IV) Fulvalene Complexes. Preparation and Structure of [CpTiPh2]-,(C10H 8)  
 Abstract    The green insoluble TiIV compound which is obtained by treating titanocene with HC1 reacts with PhLi to yield the fulvalene-bridged com pound [CpTiPh2]2(C l0H 8) 3(Ph). An X-ray struc­ ture analysis o f 3(Ph) shows, that the Ti atom s are in a trans arrangement with respect to the fulvalene group. Crystal data for 3(Ph) are as follows: C44H3gTi2, orthorhom bic, space group P 2 ,2 ,2 ,, with a = 11,3 8 5(2),/)= 14,510(2), c = 19,489(4) A, Z = 4. The crystals exhibit enan-tiomorphism. 
  Reference    Z. Naturforsch. 48b, 603 (1993); eingegangen am 28. Dezember 1992 
  Published    1993 
  Keywords    Titanium(IV) Complex, Fulvalene Ligand, Molecular Structure 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-0603.pdf 
 Identifier    ZNB-1993-48b-0603 
 Volume    48 
14Author    A.N G ArgRequires cookie*
 Title    Correlation of Mössbauer Quadrupole Splitting ( zI/?q) and Infrared Cyanide Frequency Separation in Alkali Metal Ferricyanides  
 Abstract    Mössbauer and infrared spectra of the alkali metal ferricyanides M* [Fe(CN)6] • n H 20 , where M1 = H , Li and N a were studied at room temperature. All the three compounds displayed a doublet with small quadrupole splitting (AEq). Infrared spectra of these compounds in solid state gave two frequencies for C = N stretching vibrations with their separation (Av) in increasing order which was found to be linearly correlated with AEq. A plausible explanation has been given in terms of the interaction of Li+ and Na+ cations w ith the CN-ligands of octahedrally symmetric ferricyanide anion [Fe(CN)6] 3-similar to that of hydrogen atoms which are hydrogen bonded in H 3Fe(CN)6. 
  Reference    (Z. Naturforsch. 30b, 96—98 [1975]; received February 1 /September 3 1974) 
  Published    1975 
  Keywords    Mössbauer Effect, IR Spectra, Ferricyanide Complexes, Hydrogen Bonding, Molecular Structure 
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 TEI-XML for    default:Reihe_B/30/ZNB-1975-30b-0096.pdf 
 Identifier    ZNB-1975-30b-0096 
 Volume    30 
15Author    Peter Paetzold, Peter Böhm, Anette Richter, Ernst SchollRequires cookie*
 Title    Synthese, Basenaddition und Fragmentierung der 1.3.2-Dioxaborolan-4-one Synthesis, Addition of Bases, and Fragmentation of l,3,2-Dioxaborolane-4-ones  
 Abstract    2,5,5-Triorgano-l,3,2-dioxaborolane-4-ones RB(-O-CO-CXY-O-) (2-6) can be prepared from a-hydroxycarboxylic acids XYC(OH)-COOH and dihalogenoorganoboranes RBHal2. They are much weaker Lewis acids than the 2-organo-l,3,2-dioxaborolane-4,5-diones RB(-O-CO-CO-O-) (1). The compounds 1 give 1:1 adducts with the bases DINO, MANO, PyO, and PSy, respectively; the crystal structure determination of If • DINO reveals a simple BO-coordination between the components. On electron impact, the chief fragmen-tation path is the elimination of C02 from compounds 1-6. The thermal degradation of 2-6 seems to be rather complicated in the liquid phase but is unique in the gaseous phase forming the compounds (RBO)3, CO, and XYC = 0. 
  Reference    (Z. Naturforsch. 31b, 754—764 [1976]; eingegangen am 5. Dezember 1975/8. März 1976) 
  Published    1976 
  Keywords    Dioxaborolanones, Molecular Structure, Mass Spectra, Crystal Structure, Gas-phase Thermolysis 
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 TEI-XML for    default:Reihe_B/31/ZNB-1976-31b-0754.pdf 
 Identifier    ZNB-1976-31b-0754 
 Volume    31 
16Author    Jochen Ellermann, HelmutA. Lindner, Horst Schössner, Gerhard Thiele, Gerd ZoubekRequires cookie*
 Title    Chemie poly funktioneller Liganden, 48 [1] Synthese, Schwingungsspektren, Molekül-und Kristallstruktur eines Organocyclotriarsan-pentacarbonylchrom-Komplexes Chemistry of Polvfunctional Ligands, 48 [1] Synthesis, Vibrational Spectra, Molecular and Crystal Structure of an Organocyclotriarsane-pentacarbonylchromium Complex  
 Abstract    The organocyclotriarsane, CH3C(CH2As)3 (1), reacts with chromium hexacarbonyl on ultraviolet irradiation to give the complex CH3C(CH2As)3Cr(CO)5 (2), in which the cyclo-triarsane is behaving as a monodentate ligand. The crystal structure of 2 has been determinated by X-ray diffraction. The monoclinic unit cell (space group P2i/n) contains 4 isolated molecules in a hexagonal closest packing. The mass spectrum of 2 shows the parent peak and clear fragmentation patterns. The infrared and Raman spectra are reported for 1 and 2 in the 3000-30 cm -1 region. Most of the fundamental vibrations are assigned. 
  Reference    Z. Naturforsch. 33b, 1386—1392 (1978); eingegangen am 10. Oktober 1978 
  Published    1978 
  Keywords    Organocyclotriarsane-pentacarbonylchromium Complex, Vibrational Spectra, Crystal Structure, Molecular Structure 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-1386.pdf 
 Identifier    ZNB-1978-33b-1386 
 Volume    33 
17Author    R. Tacke, M. Strecker, W. S. Sheldrick, E. Heeg, B. Berndt, K. M. KnapsteinRequires cookie*
 Title    Sila-Pharmaka, 14. Mitt. [1] Darstellung und Eigenschaften sowie Kristall-und Molekülstruktur von Sila-Difenidol Sila-Drugs, 14 th Communication [1] Preparation and Properties as well as Crystal and Molecular Structure of Sila-Difenidol  
 Abstract    Sila-difenidol (6 b), a sila-analogue of the drug difenidol (6 a), was synthesized according to Scheme 1. 6 b and its new precursors 3 and 5 were characterized by their physical and chemical properties, and their structures confirmed by elementary analyses, *H NMR and mass spectroscopy. 6 b crystallizes orthorhombic P 2i 2i 2i with a — 11.523(1), b = 14.366(4), c = 11.450(1) A, Z = 4, Dber = 1.14 gcm-3. The structure was refined to fi = 0.050 for 1897 reflexions. A strong nearly linear intramolecular 0-H---N hydrogen bond of 2.685 A is observed. The anticholinergic, histaminolytic and musculotropic spasmolytic activities of 6 a and 6 b are reported. 
  Reference    Z. Naturforsch. 34b, 1279—1285 (1979); eingegangen am 16. März 1979 
  Published    1979 
  Keywords    Sila-Difenidol, Syntheses, Crystal Structure, Molecular Structure, Biological Activity 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-1279.pdf 
 Identifier    ZNB-1979-34b-1279 
 Volume    34 
18Author    Fritz Seel, Rudi Lehnert, Eckhard Bill, Alfred TrautweinRequires cookie*
 Title    Produkte der Umsetzung des Pentacarbonyleisens mit N-substituierten Imidazolen Products of the Reaction of Pentacarbonyl Iron with N-Substituted Imidazoles  
 Abstract    1-Methyl-, 1-ethyl-, 1,2-dimethyl-and 1,2,3,4-tetramethylimidazole react with penta-carbonyliron to yield [FeIm6][Fe(CO)8] (1), [FeIm6][Fe(CO)4]2 (2), [FeIm4][Fe(CO)4] (3) and Fe(Im)(CO)2 (4) (Im = substituted imidazole). The crystal and molecular structures of 1 and 2 have been determined by X-ray diffraction. For 1 and 2 agreement between calculated and measured Mössbauer absorption intensities was obtained by taking into account Debye-Waller-factors, which were derived from the X-ray diffraction experiments. 
  Reference    Z. Naturforsch. 35b, 631—638 (1980); eingegangen am 18. Dezember 1979 
  Published    1980 
  Keywords    Imidazole Derivatives, Pentacarbonyl Iron, Crystal Structure, Molecular Structure, Mößbauer Spectra 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0631.pdf 
 Identifier    ZNB-1980-35b-0631 
 Volume    35 
19Author    Ulf Thewalt, Bernhard MüllerRequires cookie*
 Title    S4X4 and its Derivatives: Preparation. Structure and Thermolysis of CuBr * S4X4  
 Abstract    The crystalline black polymeric Cui complex CuBr • S4N4 can be prepared in high yield from Cu(NÜ3)2 • 3 HoO, NH4Br and S4N4 in methanol. An X-ray structure analysis shows that it is isostructural with CuCl • S4N4. The crystals contain [CuBr]^ chains and the Cu atoms of adjacent chains are bridged by S4N4 groups. The Cu atoms have an almost tetrahedral coordination. Tho l,3-N,N'-bonded S4N4 group has the same conformation and, within narrow limits, the same dimensions as free S4N4. Thermolysis of CuBr • S4N4 at 180 C C yields among other products CuBr, S4N4, and S2N2. 
  Reference    Z. Naturforsch. 37b, 828—831 (1982); eingegangen am 17. Februar 1982 
  Published    1982 
  Keywords    Copper(I) Complex, Tetrasulfurtetranitrid Adduct, Disulfurdinitrid, Molecular Structure, Inorganic Polymer 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0828.pdf 
 Identifier    ZNB-1982-37b-0828 
 Volume    37 
20Author    ErnstOtto Fischer, Jiabi Chen, Ulrich SchubertRequires cookie*
 Title    Übergangsmetall-Carben-Komplexe, CXXVI [1] Darstellung und Struktur symmetrischer Hydroxycarben-Anhydrid-Komplexe des Mangans und Rheniums Transition Metal Carbene Complexes, CXXVI [1] Preparation and Structure of Symmetrica! Hydroxycarbene Anhydride Complexes of Manganese and Rhenium  
 Abstract    Symmetrical anhydrides of hydroxycarbene complexes of manganese and rhenium, [JT-C5H5(C0)2MC(R)]20, (M = Mn, Re) are prepared by reaction of cationic carbyne com-plexes [.T-C5HÖ(CO)2MCR]BX4 with the corresponding metal carbonyl acylates Li[7r-C5H5(C0)2MC(0)R]. [^-C5H5(CO)2MnC(C6H5)]20 is also obtained by controlled hydrolysis of Tr-CsH^CO^MnCXBrJCeHs. The new complexes are characterized spectro-scopically and by an X-ray structure analysis of [jr-CsH^CO^MnQCeHs^O. Bei der Reaktion von Pentacarbonyldiethyl-aminocarbin-chrom-tetrafluorborat, [(CO)5CrCNEt2]BF4, mit NMe4[(C0)5MC(0)R] (M = Cr, W) entstehen die gemischten Hydroxy-carben-Anhydrid-Komplexe 
  Reference    Z. Naturforsch. 37b, 1284—1288 (1982); eingegangen am 7. Juni 1982 
  Published    1982 
  Keywords    Cationic Carbyne Complexes, Metal Acylates, Bromocarbene Complex, Molecular Structure 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1284.pdf 
 Identifier    ZNB-1982-37b-1284 
 Volume    37