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1999 (1)
1998 (1)
1Author    Z. Akdeniz, M. P. TosiRequires cookie*
 Title    Ionic Conduction and Molecular Structure of Molten FeCl 3  
 Abstract    Former experiments on molten FeCl 3 have shown that, as for A1C1 3 , melting is accompanied by a transition from sixfold to essentially fourfold coordination. However, in contrast to AICI3, the FeCl 3 melt near freezing has an appreciable ionic conductivity. We propose a model for the structure of FeCl 3 melt as consisting of closely packed Fe 2 Cl 6 bitetrahedral molecules in equilibrium with (Fe 2 Cl 5) + and (Fe 2 Cl 7)" ionised species. 
  Reference    Z. Naturforsch. 53a, 960—962 (1998); received November 18 1998 
  Published    1998 
  Keywords    Melting, Liquid Structure, Molecular Liquids 
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 TEI-XML for    default:Reihe_A/53/ZNA-1998-53a-0960.pdf 
 Identifier    ZNA-1998-53a-0960 
 Volume    53 
2Author    G. Abed, SalimM. KhalilRequires cookie*
 Title    Amel  
 Abstract    MINDO-forces calculations have been performed on the uncatalysed and acid-catalysed Friedel-Crafts reaction between CH 3 F and CH 4 . It has been found that the catalysed reaction is exothermic, spontaneous and has a smaller potential-energy barrier than the uncatalysed reaction. The mechanisms for uncatalysed and catalysed reactions are discussed. 
  Reference    Z. Naturforsch. 54a, 251—255 (1999); received December 22 1998 
  Published    1999 
  Keywords    Melting, Liquid Structure, Molecular Liquids 
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 TEI-XML for    default:Reihe_A/54/ZNA-1999-54a-0251.pdf 
 Identifier    ZNA-1999-54a-0251 
 Volume    54