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'Mixed Ligand Complexes' in keywords Facet   Publication Year 1998  [X]
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1998[X]
1Author    Andreas Voigt3, Ulrich Abramb, Reinhard Kirmse3Requires cookie*
 Title    Zur Existenz von [ReNCl4.nF,|]' (n = 1-3) Nitridorhenat(VI)-Gemischt- ligandkomplexen -Eine EPR-Untersuchung EPR Evidence of [ReNCl4_ "F J~ (n = 1-3) Nitridorhenate(VI) Mixed-Ligand Complexes  
 Abstract    The formation of mixed-ligand complexes of the type [RevlNCl4_"Fn]_ (n = 1 -3) during the reaction of [ReVINCl4]~ with [ra-(C4H9)4N]F, KF, and HF is reported. Evidence of the individual mixed-ligand compounds is given by their EPR spectral data. In frozen solutions a specific dependence of the EPR data on the composition of the coordination sphere could be detected. This is shown (i) by a nearly linear dependence of gy and A| Re on the Cl/F-content of the [ReVINCl4_"F"]-unit (additivity rules) and (ii) by well-resolved l9F hyperfine splittings. 
  Reference    Z. Naturforsch. 53b, 1183—1187 (1998); eingegangen am 9. Juni 1998 
  Published    1998 
  Keywords    Rhenium Complexes, Nitrido Complexes, Mixed-Ligand Complexes, EPR Data 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-1183.pdf 
 Identifier    ZNB-1998-53b-1183 
 Volume    53