| | 1 | Author
| Heinz Rupp, K., Jozef Verplaetse, Rene Lontie | Requires cookie* | | | Title
| Binuclear Copper Electron Paramagnetic Resonance Signals of a-Methemocyanin of Helix pomatia  | | | | Abstract
| The binuclear electron paramagnetic resonance signals o f a-methemocyanin o f Helix pomatia were investigated at liquid helium temperatures. These signals were completely eliminated by the addition of fluoride and enhanced in the presence o f chloride, which did not alter the saturation behavior. The triplet nature of the signal at g = 4.59 was confirmed by the low power-saturation. The addition of nitrite at pH 5.0 and 0° C yielded slowly and reversibly a seven-line half-field signal. On lowering the temperature the intensity of the triplet signals increased to the lowest tem perature reached 4.2 K, excluding a strong exchange coupling. | | | |
Reference
| Z. Naturforsch. 35c, 188—192 (1980); received September 18/November 17 1979 | | | |
Published
| 1980 | | | |
Keywords
| Copper, Electron Paramagnetic Resonance, Hemocyanin, Microwave Power Saturation | | | |
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| default:Reihe_C/35/ZNC-1980-35c-0188.pdf | | | | Identifier
| ZNC-1980-35c-0188 | | | | Volume
| 35 | |
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