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1983 (1)
1Author    Reinhold Tacke, Haryanto Linoh, Burghard Stumpf, Wolf-Rainer Abraham, Klaus Kieslich, Ludger ErnstRequires cookie*
 Title    Mikrobiologische Umwandlung von Silicium-Yerbindungen: Enantioselektive Reduktion von Acetessigsäure-(trimethylsilylalkyl)estern und deren Carba-Analoga Microbiological Transformation of Silicon Compounds: Enantioselective Reduction of Trimethylsilylalkyl Acetoacetates and their Carba-Analogues  
 Abstract    The trimethylsilylalkyl acetoacetates 1 b and 2 b as well as their carba analogues 1 a and 2 a have been reduced microbiologically by Kloeckera corticis (ATCC 20109), leading to the corresponding (+)-3(£)-hydroxybutanoates 3b, 4b, 3a, and 4a. The enantiomeric purity was found to be 80% (3a, 3b, 4b) and 65% (4a), respectively. The reduction of lb and 2b is -to our knowledge -the first example for a controlled microbiological transformation of organosilicon substrates. 
  Reference    Z. Naturforsch. 38b, 616—620 (1983); eingegangen am 8. Dezember 1982 
  Published    1983 
  Keywords    Silicon Compounds, Microbiological Transformation, Enantioselective Reduction 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0616.pdf 
 Identifier    ZNB-1983-38b-0616 
 Volume    38