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1978 (1)
1Author    Wolfgang Haubold, Armin Gemmler, Ullrich KraatzRequires cookie*
 Title    Tetramethylsilan -ein Methylierungsreagenz für Bortrihalogenide Tetramethylsilane -a Methylating Agent for Borontrihalides  
 Abstract    The interaction of tetramethylsilane and BY3 (Y = Br, I) in a 1:1 ratio at elevated temperature yields quantitatively MesSiY (Me = CH3) and MeBY2, while a 2:1 ratio gives 2 moles MesSiY and Me2BY. Except for MeBl2 the reactions are convenient routes for the preparation of these compounds. -Using CD3BI2 the reaction path of the formation of MP2BI was studied. 
  Reference    Z. Naturforsch. 33b, 140—141 (1978); eingegangen am 21. Dezember 1977 
  Published    1978 
  Keywords    Tetramethylsilane, Tribromoborane, Triiodoborane, Synthesis, Methylboronhalides 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0140.pdf 
 Identifier    ZNB-1978-33b-0140 
 Volume    33