| | 1 | Author
| Rolf Minkwitz, Ulrike Lohmann, Hans Preut | Requires cookie* | | | Title
| Methansulfinylchlorid-Lewissäure  | | | | Abstract
| Addukte CH3S(Cl)OMF5 (M = As, Sb) und Kristallstruktur von CH3S(Cl)OSbCl5 [1] Methanesulfinylchloride Lewis Acid Adducts CH3S(Cl)OMF5 (M = As, Sb) and Crystal Structure of CH3S(Cl)OSbCl5 [1] CH 3S(0)C1 reacts in HF as solvent with MF5 (M = As, Sb) to give products CH 3S(Cl)OMF5 (M = As, Sb). The new compounds are stable below 253 K and were charac terized by Raman and N M R spectroscopy. In addition, the crystal structure of C H 3S(Cl)OSbCl5 has been determinated. The complex crystallizes in the monoclinic space group P2x !n with a = 644.3(5), b = 1905.9(14), c = 900.0(7) pm, ß = 99.27(6)° with four formula units per unit cell. | | | |
Reference
| Z. Naturforsch. 51b, 133—138 (1996); eingegangen am 6. Juni 1995 | | | |
Published
| 1996 | | | |
Keywords
| Methanesulfinylchloride Lewis Acid Complexes, Preparation, Raman Spectra, N M R Spectra, Crystal Structure | | | |
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| default:Reihe_B/51/ZNB-1996-51b-0133.pdf | | | | Identifier
| ZNB-1996-51b-0133 | | | | Volume
| 51 | |
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