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'Methanesulfinylchloride Lewis Acid Complexes' in keywords
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1996 (1)
1Author    Rolf Minkwitz, Ulrike Lohmann, Hans PreutRequires cookie*
 Title    Methansulfinylchlorid-Lewissäure  
 Abstract    Addukte CH3S(Cl)OMF5 (M = As, Sb) und Kristallstruktur von CH3S(Cl)OSbCl5 [1] Methanesulfinylchloride Lewis Acid Adducts CH3S(Cl)OMF5 (M = As, Sb) and Crystal Structure of CH3S(Cl)OSbCl5 [1] CH 3S(0)C1 reacts in HF as solvent with MF5 (M = As, Sb) to give products CH 3S(Cl)OMF5 (M = As, Sb). The new compounds are stable below 253 K and were charac­ terized by Raman and N M R spectroscopy. In addition, the crystal structure of C H 3S(Cl)OSbCl5 has been determinated. The complex crystallizes in the monoclinic space group P2x !n with a = 644.3(5), b = 1905.9(14), c = 900.0(7) pm, ß = 99.27(6)° with four formula units per unit cell. 
  Reference    Z. Naturforsch. 51b, 133—138 (1996); eingegangen am 6. Juni 1995 
  Published    1996 
  Keywords    Methanesulfinylchloride Lewis Acid Complexes, Preparation, Raman Spectra, N M R Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0133.pdf 
 Identifier    ZNB-1996-51b-0133 
 Volume    51