1 | Author | H. Schmidbaur, G. Blaschke | Requires cookie* |
Title | Ein Ylidkomplex des Rutheniums mit drei-und viergliedrigen Metallocyclen An Ylide Complex of Ruthenium with Three-and Four-Membered Metallocycles ![]() | ||
Abstract | A spirometallocyclic complex of ruthenium with (CH3)2P(CH2)2, (CH3)2PCH2 and two (CH3)3P ligands (formula 5) is synthesized from (CH3)2P(CH2)2Li and frans-[(CH3)3P]4RuCl2 in the molar ratio 2:1. Two equivalents of (CHs^P are liberated and the ionic complex frans-[(CH3)3P]4Ru[CH2P(CH3)3]Cl + Cl _ is formed as a by-product. The products were characterized by analytical and spectroscopic data. | ||
Reference | Z. Naturforsch. 35b, 584—587 (1980); eingegangen am 11. November 1979 | ||
Published | 1980 | ||
Keywords | Ylide Complexes, Ruthenium, Metallocycle | ||
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