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'Metal Carbonyl' in keywords Facet   Publication Year 1980  [X]
Facet   section ZfN Section B  [X]
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1Author    Manfred Fild, Wolfgang Handke, WilliamS. SheldrickRequires cookie*
 Title    Methylen Verbindungen von Nichtmetallen, III [1] Metallcarbonyl-Komplexe mit methylenverbrückten Diphosphor-Liganden Methylene Compounds of Non-Metals, III [1] Metal Carbonyl Complexes of Methylene-Bridged Diphosphorus Ligands  
 Abstract    Compounds of the type R2PCH2PR2 (R = Pr«0, Me2N) react with cis-LM(CO)4 (L = Bicyclo[2,2,l]hepta-2,5-dien; M = Cr, Mo, W) complexes to yield cis-substituted [R2PCH2PR2]M(CO)4 derivatives. The structure of the molybdenum compound, [(Pr i O)2PCH2P(OPr i)2]Mo(CO)4, has been determined. Diphosphorus ligands of the type R2P(S)CH2PR2 (R = F, Pr*0) are monodentate and form [R2P(S)CH2PR2]2Mo(CO)4 complexes, whereas the compound (Me2N)2P(S)CH2P(NMe2)2 acts as a bidentate ligand. 
  Reference    Z. Naturforsch. 35b, 838—842 (1980); eingegangen am 20. Februar 1980 
  Published    1980 
  Keywords    Metal Carbonyls, Diphosphorus Ligands, X-ray 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0838.pdf 
 Identifier    ZNB-1980-35b-0838 
 Volume    35