| | 1 | Author
| Manfred Fild, Wolfgang Handke, WilliamS. Sheldrick | Requires cookie* | | | Title
| Methylen Verbindungen von Nichtmetallen, III [1] Metallcarbonyl-Komplexe mit methylenverbrückten Diphosphor-Liganden Methylene Compounds of Non-Metals, III [1] Metal Carbonyl Complexes of Methylene-Bridged Diphosphorus Ligands  | | | | Abstract
| Compounds of the type R2PCH2PR2 (R = Pr«0, Me2N) react with cis-LM(CO)4 (L = Bicyclo[2,2,l]hepta-2,5-dien; M = Cr, Mo, W) complexes to yield cis-substituted [R2PCH2PR2]M(CO)4 derivatives. The structure of the molybdenum compound, [(Pr i O)2PCH2P(OPr i)2]Mo(CO)4, has been determined. Diphosphorus ligands of the type R2P(S)CH2PR2 (R = F, Pr*0) are monodentate and form [R2P(S)CH2PR2]2Mo(CO)4 complexes, whereas the compound (Me2N)2P(S)CH2P(NMe2)2 acts as a bidentate ligand. | | | |
Reference
| Z. Naturforsch. 35b, 838—842 (1980); eingegangen am 20. Februar 1980 | | | |
Published
| 1980 | | | |
Keywords
| Metal Carbonyls, Diphosphorus Ligands, X-ray | | | |
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| default:Reihe_B/35/ZNB-1980-35b-0838.pdf | | | | Identifier
| ZNB-1980-35b-0838 | | | | Volume
| 35 | |
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