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'Metal Carbonyl' in keywords Facet   Publication Year 1976  [X]
Facet   section ZfN Section B:Volume 031  [X]
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1Author    Wolfgang Danzer, Wolfgang Beck, Michael KeublerRequires cookie*
 Title    Reaktionen von Metallcarbonylverbindungen mit Diaziridin 1 Reactions of Metal Carbonyls with Diaziridine  
 Abstract    Cyclic carbamoyl complexes (2) and (3) result from the reaction of metal carbonyl hydrides with 3,3-pentamethylen diaziridine (1). 1 is cleaved at the metal by reaction with substituted metal carbonyls of Mo and W formally into 'nitrene' and cyclohexanone imine, which are isolated as isocyanate and ketimine complexes, respectively. 1 forms adducts with cobalt and nickel(II) chlorides. 
  Reference    (Z. Naturforsch. 31b, 1360—1366 [1976]; eingegangen am 16. Juli 1976) 
  Published    1976 
  Keywords    Ring Opening, Diaziridine, Metal Carbonyls, Carbamoyl, Ketimine Complexes 
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 TEI-XML for    default:Reihe_B/31/ZNB-1976-31b-1360.pdf 
 Identifier    ZNB-1976-31b-1360 
 Volume    31