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1981 (1)
1Author    Joseph Grobe, Heinz Zimmermann, FrauRequires cookie*
 Title    Elektrochemische Synthesen, VII [1]  
 Abstract    Elektrochemische Substitutionsreaktionen an M(CO)6_n(PR3)M-Komplexen (M = Cr, Mo, W) Electrochemical Syntheses, VII [1] Electrochemical Substitution Reactions of M(CO)6-n(PR3)n Complexes (M = Cr, Mo, W) The principle of electrochemical substitution of metal carbonyls has been applied to monosubstituted derivatives M(CO)5PR3 (M = Cr, Mo, W) with the aim of selective prepa-ration of di-and trisubstituted products M(CO)4(PR3)(PR'3) or M(CO)3(PR3)(PR'3)2. It is shown that, due to simultaneous replacement of CO and PR3 mixtures of products are formed. 
  Reference    Z. Naturforsch. 36b, 482—484 (1981); eingegangen am 24. Oktober 1980 
  Published    1981 
  Keywords    Electrochemical Synthesis, Metal Carbonyl Derivatives, Phosphane Ligands 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0482.pdf 
 Identifier    ZNB-1981-36b-0482 
 Volume    36