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1997 (1)
1Author    Joachim Pickardt, Sven Wiese, Pirka WischlinskiRequires cookie*
 Title    Reaktionen von Cadmium-und Quecksilber(II)halogeniden und -pseudohalogeniden mit Kronenethern: Kristallstrukturen der Komplexe von Benzo-18-krone-6 mit CdX2 und HgX2 (X = CI, Br) und von Dibenzo-18-krone-6 mit Hg(CN)2 Reactions of Cadmium and Mercury(II) Halides and Pseudohalides with Crown Ethers: Crystal Structures of the Complexes of Benzo-18-crown-6 with CdX2 and HgX2 (X = Cl, Br) and of Dibenzo-18-crown-6 with Hg(CN)2  
 Abstract    The reactions of benzo-18-crown-6 with MeX2 (Me = Cd, Hg; X = Cl. Br), and of dibenzo-18-crown-6 with Hg(CN)2 afford the compounds [Me(benzo-18-crown-6)X2] (1-4) and [Hg(dibenzo-18-crown-6)(CN)2 (5), resp., the crystal structures of which were determined. They consist of isolated neutral molecules, the crystalline Cd complexes and 5 contain one molecule of water of crystallization per formula unit, which however is not coordinated to the metal atom. The metal atoms are coordinated by the six O atoms of the ligands and the two halide atoms, or the two CN groups for 5, resp., the coordination being more unsymmetrical for the benzo than for the dibenzo ligand. 
  Reference    Z. Naturforsch. 52b, 1296—1300 (1997); eingegangen am 11. August 1997 
  Published    1997 
  Keywords    Crown Complexes, Cadmium Halides, Mercuric Halides, Mercuric Cyanide, Crystal Structure 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-1296.pdf 
 Identifier    ZNB-1997-52b-1296 
 Volume    52