| 1 | Author
| Dietrich Mootz, Wolfgang Poll | Requires cookie* | | Title
| Fluoride und Fluorosäuren, VI Verbindungsbildung und Kristallstrukturen im System Ammoniak—Fluorwasserstoff [ 1 , 2 ] Fluorides and Fluoro Acids, VI Com pound Form ation and Crystal Structures in the System A m m onia-H ydrogen Fluoride  | | | Abstract
| The melting diagram of the quasi-binary system NH3— HF between the limits NH4HF: and HF was redetermined. The compounds NH 3 • 4H F. NH3 • 5HF and NH3 ■ 8HF with melting points of 26. —14 (dec.) and —95 °C (dec.), respectively, were established as the stable phases. Their crystal structures were determined as those of ammonium hydrogen fluorides NH4[F(HF)3], NH4[F(HF)4] and NH4[HF:(H F)3] • 3HF with extended N -H --F and F -H -F hydrogen bonding. | | |
Reference
| Z. Naturforsch. 39b, 290—297 (1984); eingegangen am 15. September 1983 | | |
Published
| 1984 | | |
Keywords
| System NH3 — HF, Melting Diagram Crystal Structure, Hydrogen Bonding | | |
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| default:Reihe_B/39/ZNB-1984-39b-0290.pdf | | | Identifier
| ZNB-1984-39b-0290 | | | Volume
| 39 | |
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