| | 1 | Author
| Elmar Flaskamp, -A, Gottfried Zimmermann, »., Gerhard Nonnenmacher, Otto Isaac | Requires cookie* | | | Title
| Untersuchungen zur Charakterisierung des Prochamazulens Matrizin aus Matricaria chamomilla L. Studies on the Characterization of the Chamazulene Precursor Matricine from Matricaria chamomilla L  | | | | Abstract
| The relative configuration of the thermolabile chamazulene precursor matricine has been established by NMR spectrometric studies. The NMR spectral data prove to be consistent with the well-known structure of the chamomile component. On the basis of our results the levorotatory natural substance moreover can be specified stereochemically as (—)-(3S*, 3aR*, 4S*, 9R*, 9aS*, 9bS*)-4-acetoxy -2,3,3a,4,5,9,9a,9b -octahy dro -9 -hydroxy -3,6,9 -trimethy lazuleno [4,5 -b ]furan -2 -one. | | | |
Reference
| Z. Naturforsch. 37b, 508—511 (1982); eingegangen am 24. November 1981 | | | |
Published
| 1982 | | | |
Keywords
| Matricaria chamomilla L, Matricine, NMR Spectra, Stereochemistry | | | |
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| ZNB-1982-37b-0508 | | | | Volume
| 37 | |
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