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1Author    Mit Komplexe, KupferUnd Mangan, Zink, CarstenO. Kienitz, Carsten Thöne, PeterG. JonesRequires cookie*
 Title    Zur Koordinationschemie des 2,2'-Dipyridyldiselenids (PySeSePy), Teil 2 [1]  
 Abstract    The coordination chemistry of 2,2'-dipyridyldiselenide (PySeSePy) towards mangane­ se, copper and zinc centres has been studied. The complexes [MnBr2-/V,/V'-(PySeSePy)] (1), [CuBr2-/V,/V'-(PySeSePy)] (2), [Cu-(//-Br)-7V(/V'-(PySeSePy)]2 (3), [Cu-()U-Br)-{p-N,N'-(PySeSePy)}]" (4), [Cu-(/i-Cl)-/V,W'-(PySeSePy)]2 (5), [Zn(OOCC6F5)2-/V,/V'-(PySeSePy)] (6) and [Z n (0 S 0 2CF3)2-./V>/V'-(PySeSePy)] (7) have been synthesised and the crystal structures of 1, 3, 4 and 6 determined. 1, 3 and 6 display seven-membered metallacycles with tetrahedral coordination of the metal centres. In these cases 2,2'-dipyridyldiselenide acts as a chelating ligand. In the polymeric complex 4, 2,2'-dipyridyldiselenide acts as a bridging ligand. All com­ plexes display selenium-selenium single bonds with an average length of 232 pm. In contrast to the analogous chloro and nitrato complexes, the zinc complexes 6 and 7 are not dissociated in solution, as evidenced by 77Se NMR experiments. The corresponding resonances are shifted downfield in comparison with the ligand. 
  Reference    Z. Naturforsch. 55b, 587—596 (2000); eingegangen am 3. März 2000 
  Published    2000 
  Keywords    Manganese, Copper, Zinc 
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 TEI-XML for    default:Reihe_B/55/ZNB-2000-55b-0587.pdf 
 Identifier    ZNB-2000-55b-0587 
 Volume    55 
2Author    M. A. Nabar, A. P. DalviRequires cookie*
 Title    Thermal Analysis of the Cadmium and Manganese Hydrogen Orthoarsenate Monohydrates (M HAs04 * H20, where M = Cd, Mn)  
 Abstract    The dehydration decomposition of cadmium and manganese hydrogen orthoarsenate monohydrates was studied by static isothermal and differential thermoanalytical methods. It was found that the dehydration decomposition takes place in a single stage forming the respective diarsenate, the peak minimum temperature being 458 K for the cadmium and 466 K for the manganese salt. 
  Reference    Z. Naturforsch. 33b, 1106—1 (1978); received April 17 1978 
  Published    1978 
  Keywords    Thermal Analysis, Cadmium, Manganese 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-1106.pdf 
 Identifier    ZNB-1978-33b-1106 
 Volume    33 
3Author    B. Wulff, Hk Wedel, Müller-BuschbaumRequires cookie*
 Title    Zur Kristallchemie von Telluraten mit Mn2+ im kationischen und anionischen Teil der Kristallstruktur: (Mn2?4Cuo,6)Te06, Ba2M nTe06 und Pb(Mn0,5 Te0,5 )O3 On the Crystal Chemistry of Tellurates Containing Mn2+ in the Cationic and Anionic Part of the Crystal Structure: (Mn2 4Cu0 6)Te06, Ba2MnTe06 and Pb(Mn0 5Te0 5) 0 3 L  
 Abstract    Single crystals of (Mn2.4Cu0 6)Te06 (I), Ba2MnTe06 (II) and Pb(Mn0 5Te0 5) 0 3 (III) have been prepared by crystallization from fluxes. X-ray investigations led to rhombohedric sym­ metry (I): R3, (II): R3m with the trigonal lattice constants (I): a = 8.826(1), c = 10.687(2) Ä, Z = 2. (II): a = 5.817(8), c = 14.244(3) A, Z = 3. Compound (III) crystallizes with cubic symmetry P43m, a = 4.045(3) A, Z = 1. (I) is the first example of a manganese(II) tellurate and belongs to the structure type of A3X 0 6 compounds like (Mn2In)Sb06, Mn3W 0 6 and Ca3U 0 6. (II) exemplifies an ordered and (III) a disordered variation of the perovskites. 
  Reference    (Z. Naturforsch. 53b, 49—52 [1998]; eingegangen am 15. Oktober 1997) 
  Published    1998 
  Keywords    Manganese, Copper, Lead, Barium, Tellurates 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-0049.pdf 
 Identifier    ZNB-1998-53b-0049 
 Volume    53 
4Author    Z. NaturforschRequires cookie*
 Title    Ag+ als Substituent eines Alkalimetalls in Ag2SrMnV20 8  
 Abstract    Single crystals of Ag2 SrM nV20 8 have been prepared by reactions of metallic silver and a mixture of S rC 0 3, M nC 03 HoO and V ?0 5. X-Ray investigations showed monoclinic symmetry, space group Cfh-C2/c, a = 9.7022(9), b = 5.5882(5), c = 13.894(1), ß = 90.41(1)°, Z = 4. The crystal structure is isotypic to N a2BaCuV20 8 and includes V 0 4 tetrahedra, M n 0 6 octahedra as well as irregular A g 0 8 and S rO !0 polyhedra. Ag2SrM nV20 8 is characterized by a [MnV20 8] network incorporating Ag+ and S r + or a [Ag2V 2Ö 8] frame incorporating Mn2+ and Sr2+ ions. Ag+ is able to replace an alkali ion in the cationic part of the crystal structure. 
  Reference    Z. Naturforsch. 53b, 279—282 (1998); eingegangen am 17. November 1997 
  Published    1998 
  Keywords    Silver, Strontium, Manganese, Vanadium Oxide 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-0279.pdf 
 Identifier    ZNB-1998-53b-0279 
 Volume    53 
5Author    Hk Wulff, Müller-BuschbaumRequires cookie*
 Title    Isolierte trigonale S r 0 6-Prismen verknüpfen Kagome-Netze im Strontium-Manganat(I V)-Tellurat( VI): SrMnTe06 Kagome Layers Connected by Isolated Trigonal Sr06 Prisms in the Strontium Manganate(IV) Tellurate(VI): SrMnTe06 L  
 Abstract    Single crystals of the hitherto unknown compound SrM nT e06 have been prepared from Sr(0H)2-8H20 , M n C 0 3(aq) and T e 0 2 in air by crystallization below the melt range. X-ray in­ vestigations showed hexagonal symmetry, space group D3h-P62m, lattice constants a = 5.143(1), c = 5.384(2) A, Z = 1. SrM nTe06 is characterized by staggered [(Mn/Te)60 18] Kagome layers along [001]. These layers are connected by Sr2+ ions, resulting in S r0 6 prisms isolated from each other. The structure is discussed with respect to the connection of Kagome nets in the quaternary oxides of the Ba3Ln40 9 type. 
  Reference    Z. Naturforsch. 53b, 283—286 (1998); eingegangen am 7. November 1997 
  Published    1998 
  Keywords    Strontium, Manganese, Tellurate, Crystal Structure 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-0283.pdf 
 Identifier    ZNB-1998-53b-0283 
 Volume    53 
6Author    Requires cookie*
 Title    Reaktionen von Metallcarbonylen mit Diazirin1  
 Abstract    W o l f g a n g B e c k u n d W o l f g a n g D a n z e r Pentamethylendiazirine (N = N) has been found in metal carbonyl compounds as a monodentate two electron ligand (7t-CH3C5H 4Mn(CO)2 N = N , (OC)sW N = N) or as a 
  Reference    (Z. Naturforsch. 30b, 716—719 [1975]; eingegangen am 2. Juni 1975) 
  Published    1975 
  Keywords    Diazirine Carbonyl Complexes, Manganese, Iron, Molybdenum, Tungsten 
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 TEI-XML for    default:Reihe_B/30/ZNB-1975-30b-0716.pdf 
 Identifier    ZNB-1975-30b-0716 
 Volume    30 
7Author    Albrecht MewisRequires cookie*
 Title    AB2X2-Verbindungen im CaAl2Si2-Typ, V [1] Zur Struktur der Verbindungen CaMn2P2, CaM^As*, SrMn2P2 und SrMn2As2  
 Abstract    Four ternary compounds with the formulas CaMn2P2, CaMn2As2, SrMn2P2, and SrMn2As2 have been prepared and investigated by X-ray methods. They are isotypic and crystallize trigonally in a CaAl2Si2-type structure (space group P 3 m 1-D3d) with the lattice constants: 
  Reference    Z. Naturforsch. 33b, 606—609 (1978); eingegangen am 20. März 1978 
  Published    1978 
  Keywords    Strontium Compounds, Calcium Compounds, Manganese, Phosphides, Arsenides 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0606.pdf 
 Identifier    ZNB-1978-33b-0606 
 Volume    33 
8Author    Ekkehard Lindner, Günter Von Au, Hans-Jürgen EberleRequires cookie*
 Title    Darstellung und Eigenschaften von und Reaktionen mit metallhaltigen Heterocyclen, I Metallorganische Komplexe von Mangan und Rhenium mit zwei funktionellen Zentren Preparation and Properties of and Reactions with Organometallic Heterocycles, I Organometallic Complexes of Manganese and Rhenium with two Functional Centres  
 Abstract    The binuclear anions Na2[(0C)4MP(0)R2]2 (2a, a', b, b') [M = Mn: R = CH3 (a), C6H5 (a'); M = Re: R = CH3 (b), CßHs (b')] can be obtained quantitatively by reduction of the phosphinic acid complexes (OC)4BrMP(OH)R2 (la, a', b, b') with sodium amalgam in ether. While the manganate anions 2 a, a' can be transformed with excess sodium into the mononuclear salts Na2[(0C)4MnP(0)R2] (3 a, a'), with two nucleophilic centres, the corresponding anions 2 b, b' eliminate CO to give sparingly soluble species. From 3 a, a' and dimethylsulphate the doubly methylated compounds CH3Mn(CO)4P(OCH3)R2 (4a, a') are obtained. The rhenium derivatives CH3Re(CO)4P(OCH3)R2 (4b, b') are formed only in very poor yields from 2 b, b' and dimethylsulphate under reductive conditions. The IR, *H NMR, and mass spectra are discussed. 
  Reference    Z. Naturforsch. 33b, 1296—300 (1978); eingegangen am 29. Juni 1978 
  Published    1978 
  Keywords    Carbonyl Phosphinito Anions, Manganese, Rhenium, Functional Centres, IR 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-1296.pdf 
 Identifier    ZNB-1978-33b-1296 
 Volume    33 
9Author    ChrL. TeskeRequires cookie*
 Title    Darstellung, Kristallstrukturdaten und Eigenschaften der quaternären Thiostannate(IV) BaZnSnS4 und BaMnSnS4 Preparation, Crystal Data and Properties of the Quaternary Thiostannates(IV) BaZnSnS4 and BaMnSnS4  
 Abstract    BaZnSnS4 and BaMnSnS4 were prepared for the first time and the atomic positions of the crystal structure were refined. Both compounds crystallize isotypically with BaCdSnS4 [1]. Space group C^-Fdd2 (No. 43) orthorhombic. BaZnSnS4: a = 2196,4; b = 2150,4; c = 1270,i pm; BaMnSnS4: a = 2173,i; b = 2144,9; c -1259,i. 
  Reference    Z. Naturforsch. 35b, 509—510 (1980); eingegangen am 30. Oktober 1979 
  Published    1980 
  Keywords    Crystal Structure, Interatomic Distances, Zinc, Manganese, Sulfur 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0509_n.pdf 
 Identifier    ZNB-1980-35b-0509_n 
 Volume    35 
10Author    HeinzDieter Lutz, SalehM. El-Suradi, Christiane Mertins, Bernward EngelenRequires cookie*
 Title    Zur Kenntnis der Hydrate des Mangan-und Zinksulfits. Röntgenographische, thermoanaly tische, Raman-und IR-spektroskopische Untersuchungen  
 Abstract    X-ray, IR and Raman data as well as thermoanalytical measurements (DTA, TG, and DTG) of several new hydrates, viz. MnS03 • 2 1 /z H20, MnS03 • 2 H20, ZnS03 • 3 H20, /S-ZnS03 • 2 1 /2 H20, and y-ZnS03 • 2 x /2 H20, and of previously reported hydrates in the systems MnS03-H20, ZnS03-H20, and MnS03-ZnS03-H20 are presented. Furthermore, the formation of mixed crystals is studied in the system MnS03-ZnS03-H20. The following crystal data have been determined by single crystal measurements: MnS03 • 2 1 /2 H20 (P4i2i2):a = b = 968.4(1), c = 1040.9(1) pm, Z = 8, MnS03 • 2 H20 (P2i/w):a = 650.9(1), b = 873.8(1), c = 774.7(1) pm, ß = 99.80(1)°, Z = 4, ZnS03 • 3 H20 (Pnma): a = 953.6(1), b = 553.0(1), c = 941.9(1) pm, Z = 4, ß-ZnS03 • 21/2 H20 (P4i2!2): a = b = 952.1(1), c = 1025.4(1) pm, Z = 8, y-ZnS03 • 2 X \2 H20 (with small amount of Mn 2 +) (o-rh.): a = 1493(1), b = 1812(2), c = 753(1) pm, Z = 16, ZnS03 • 1/2 H20 (mon.): a = 1326.7(5), b = 706.3(2), c = 834.4(1) pm, ß = 117.41(3)°, Z = 8. The IR spectra show that, with the exception of y-ZnS03 • 2 x /2 H20, both weak and strong hydrogen bonds are present in the sulfite hydrates. Under an S02 atmosphere the sulfite hydrates can be dehydrated without simultaneous dissociation to the oxide and sulfur dioxide. The isotypic hydrates /?-MnS03 • 3 H20 and ZnS03 • 3 H20 (ß-MnSÖ3 • 3 H20 type), and MnS03 • 2 H20 and ZnS03 • 2 H20 (ZnSe03 • 2 H20 type) form complete mixed crystal series. Solid solutions are also formed from a-MnS03 • 3 H20 (a-FeS03 • 3 H20 type), y-ZnS03 • 2 l /2 H20, MnS03 • 1 H20, and ZnS03 • 1 /2 H20. No incorporation of Mn or Zn could be observed for a-ZnS03 • 2Va H20 and the isotype hydrates MnS03 • 2!/a H20 and ß-ZnS03 • 2 1 /2 H20 (CoS03 • 21/2 H20 type). 
  Reference    Z. Naturforsch. 35b, 808—816 (1980); eingegangen am 17. Dezember 1979 
  Published    1980 
  Keywords    Sulfite, Hydrates, Manganese, Zinc, X-ray 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0808.pdf 
 Identifier    ZNB-1980-35b-0808 
 Volume    35 
11Author    Joachim Von Seyerl, Gottfried Huttner, Karl KrügerRequires cookie*
 Title    Acetylaceton als Dien-Diolat-Ligand in 6-Methyl-4-methylen-2-phenyl-4H-1.3.2-dioxa-arsorin- Übergangsmetallkomplexen Acetylacetone as a Diene Diol Ligand in 6-Methyl-4-methylen-2-phenyl-4H-l,3,2-dioxa-arsorine Transition Metal Complexes  
 Abstract    of dichlorophenylarsane complexes with acetylacetone gives 1,3,2-dioxa arsorine systems, in which both chlorine functions are substituted by the oxygen atoms of one acetylacetone moiety bonded in its diene diol form. Properties and spectra of (C0)5CrAsPh(C5H602) and 7?5.c5H5(C0)2MnAsPh(C5H602) are described; the structure of the (CO)öCr complex was established by an X-ray analysis. 
  Reference    Z. Naturforsch. 35b, 1552—1554 (1980); eingegangen am 20. August 1980 
  Published    1980 
  Keywords    Arsorine Systems, Chromium, Manganese, X-ray Reaction 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1552.pdf 
 Identifier    ZNB-1980-35b-1552 
 Volume    35 
12Author    Werner Winter, Reinhard Merkel, Udo KunzeRequires cookie*
 Title    Koordinationschemie funktioneller Phosphorylide, V [1] Die Molekülstrukturen der isomorphen Mangan-und Rheniumbromtricarbonyl- komplexe von 2-Methyl-2-(triphenylphosphonio)dithiopropionat Coordination Chemistry of Functional Phosphorus Ylides, V [1] The Molecular Structures of the Isomorphous Manganese and Rhenium Bromotricarbonyl Complexes of 2-Methyl-2-(triphenylphosphonio)dithiopropionate  
 Abstract    The isomorphous crystal structures of the manganese and rhenium bromotricarbonyl complexes 2 a, b have been determined at room temperature (Mn) and at —110 °C (Mn, Re; P2x/c, Z — 4). At room temperature, data collection is accompanied by crystal decomposi-tion, and a cleavage of the PPh3 group is suggested by the results as the primary process. The same initial step is thought to be valid for the photodecomposition in solution. The main structural difference between the free and coordinated betaine ligand 1 is the reduced electrostatic interaction of P and S in the complexed form. Einführung 
  Reference    Z. Naturforsch. 38b, 747—751 (1983); eingegangen am 20. März 1983 
  Published    1983 
  Keywords    Manganese, Rhenium, Betaine Complexes, Dithiocarboxylate Complexes, X-Ray 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0747.pdf 
 Identifier    ZNB-1983-38b-0747 
 Volume    38 
13Author    CorneliusG. Kreiter, Klaus LehrRequires cookie*
 Title    Photochemische Reaktionen von Übergangsmetall-Organyl-Komplexen mit Olefinen, VI [1] Reaktionen von Tricarbonyl-T]5-2,4-cyclohexadienyl-mangan mit konjugierten Dienen Photochem ical Reactions of Transition Metal Organyl Complexes with Olefins, VI [1] Reactions o f Tricarbonyl (^5-2,4-cyclohexadienyl)manganese with Conjugated Dienes  
 Abstract    Tricarbonyl-?/5-2,4-cyclohexadien-l-yl-manganese (1) was reacted photochemically at 253 K with simple conjugated dienes. Four different types of products were obtained, depending upon the dienes. With 1,3-butadiene (A) dicarbonyl-743-l-(3-buten-l,2-diyl)-2,4-cyclohexa-diene-manganese (2 A) is isolated. 2-Methyl-1,3-butadiene (B) yields the methyl-substituted diastereomeric dicarbonyls 2B, 2B', the [4+5]-cycloadduct tricarbonyl-//3:2-3-methyl-bicyclo-[4.3. l]-3,8-decadien-7-yl-manganese (3B) and tetracarbonyl-?/3-4-methylene-bicyclo[4.3. l]-8-decen-3-yl-manganese (4B) with an exocyclically coordinated tetracarbonylm anganese frag­ ment. W ith 2,3-dimethyl-1,3-butadiene (C) only the [4+5]-cycloadduct 3C and the tetracar-bonyl 4C are obtained. No CC-bond formation is observed with ^,^-2,4-hexadiene (D) and 1,3-cyclohexadiene (E). Carbonyl-75-2,4-cyclohexadien-1 -yl-74-£,> £'-2,4-hexadiene-manganese (5D), and carbonyl-74-l,3-cyclohexadiene-^5-2,4-cyclohexadien-l-yl-manganese (5E) are the only products. The complexes were separated and purified by HPL chrom atography. Their constitutions were determined by IR and N M R spectroscopy. 
  Reference    Z. Naturforsch. 46b, 1377—1383 (1991); eingegangen am 4. April 1991 
  Published    1991 
  Keywords    Diene Controlled C -C Bond Form ation, Manganese, Photochemical Reactions 
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 TEI-XML for    default:Reihe_B/46/ZNB-1991-46b-1377.pdf 
 Identifier    ZNB-1991-46b-1377 
 Volume    46 
14Author    E. Klüver, Hk Müller-BuschbaumRequires cookie*
 Title    Uber einen Lanthanoid-Mangan-Apatit: Nd4M n(Si04)30 On a Lanthanoid Manganese Apatite: Nd4M n(S i04)30  
 Abstract    Single crystals of Nd4M n (S i0 4)30 have been prepared by a Bi20 3 flux in closed copper tubes. The colourless crystals show hexagonal symmetry, space group C |h-P 6 3/m, a -9,4986(9), c = 6,944(2) A, Z = 2. Nd4M n (S i0 4)30 crystallizes in the A patite structure and shows Nd3+ and Mn2+ with partly statistical distribution. A s a consequence of this, 0 (2) and 0 (4) are occupying split positions. 
  Reference    (Z. Naturforsch. 50b, 61 [1995]; eingegangen am 25. Juli 1994) 
  Published    1995 
  Keywords    Neodymium, Manganese, Silicon, Apatite, Crystal Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-0061.pdf 
 Identifier    ZNB-1995-50b-0061 
 Volume    50 
15Author    Anne Utzolino, Karsten BluhmRequires cookie*
 Title    Zur Synthese und Kristallstruktur von manganhaltigen Boratoxiden  
 Abstract    M nF e(B 03) 0 und MnAl0,5Yo,5(B03) 0 Synthesis and Crystal Structure of Manganese Borate Oxides: M nFe(B03) 0 and MnAlo.5Yo.5(B 0 3) 0 Single crystals of the compounds M n F e(B 0 3) 0 (I) and MnAlo.5Y o.5(B 03) 0 (II), were obtained by a B20 3 flux technique. I crystallizes with orthorhombic symmetry, space group D ^ -P n m a (Nr.62), a -939.92; b = 319.41; c = 939.11 pm; Z = 4 and II with monoclinic symmetry, space group C2h-P 2 i/n (Nr. 14). a = 325.6; b = 955.1; c = 929.2 pm; ß = 90.70° ; Z = 4. I is isotypic to the mineral Warwickite, while II is a distorded variant of this structure. All metal ions are octahedrally coordinated. Both structures contain isolated, trigonal planar B 0 3 units and oxygen atoms that are not coordinated to boron. 
  Reference    Z. Naturforsch. 50b, 1146—1150 (1995); eingegangen am 5. D ezem ber 1994 
  Published    1995 
  Keywords    Manganese, Iron Aluminium, Yttrium, Borate Oxide, Crystal Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1146.pdf 
 Identifier    ZNB-1995-50b-1146 
 Volume    50 
16Author    Silke Busche, Karsten BluhmRequires cookie*
 Title    Zur Synthese und Kristallstruktur von Zinkboratoxiden mit isolierten, trigonal planaren B 0 3-Baugruppen: Zn5M n(B03)20 4 und Z nF e(B 03) 0 Synthesis and Crystal Structure of Zinc Borate Oxides Containing Isolated Trigonal Planar B 0 3 Units: Z n5M n (B 0 3)20 4 and Z n F e(B 0 3) 0  
 Abstract    Single crystals of the new compounds Zn5M n (B 0 3)20 4 (A) and Z n F e (B 0 3) 0 (B) were prepared by using a B20 3 flux technique. Zn5M n (B 0 3)20 4 is isostructural with Ni5T i(B 0 3)20 4 and Z n F e (B 0 3) 0 is isotypic with the mineral warwickite. X-ray investiga­ tions on single crystals led to (A) space group D ^ -P b a m , a = 926.41(10), b = 1236.67(8), c = 304.55(3) pm, Z = 2, and (B) space group D i^ -P n m a, a = 924.62(4), b = 314.1(10), c = 935.3(2) pm, Z = 4. The structure o f Zn5M n (B 0 3)20 4 (A) contains four octahedrally coordi­ nated metal sites, one of these statistically occupied by Zn2+ and Mn4+. In the structure o f Z n F e (B 0 3) 0 the ions Zn2+ and Fe3+ occupy statistically both distorted octahedral sites. Both structures contain isolated B 0 3 units and oxygen that is not coordinated to boron. 
  Reference    Z. Naturforsch. 50b, 1450—1454 (1995); eingegangen am 25. April 1995 
  Published    1995 
  Keywords    Zinc, Manganese, Iron Borate Oxide, Crystal Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1450.pdf 
 Identifier    ZNB-1995-50b-1450 
 Volume    50 
17Author    AnneU. Tzolino, K. Arsten BluhmRequires cookie*
 Title    Synthese und röntgenographische Charakterisierung von zwei neuen Verbindungen des Ludwigit-Strukturtyps: Co5Sn(B0 3)2 0 4 und Co5Mn(B0 3 )20 4  
 Abstract    Synthesis and X -R ay C haracterization o f Two New Com pounds with Ludw igite-Structure: C o5S n (B 0 3)20 4 and C o5M n (B 0 3)20 4 The compounds Co5Sn(B 03)20 4 (I) and Co5M n(B03)20 4 (II) were prepared by using a B20 3 flux technique. Single crystals were investigated by X-ray diffraction and showed orthorhombic symmetry, space group D2h-Pbam (No. 55), I a = 944.4; b = 1233.8; c = 310.5 pm; Z = 2 and II a = 925.07; b = 1241.67; c = 305.24 pm; Z = 2. Both compounds are isotypic to the mineral Ludwigite. All metal point positions show an octahedral oxygen coordination. Co2+ and M4+ (M = Sn or Mn) occupy one point position statistically. Both structures contain isolated, trigonal planar B 0 3 units and oxygen atoms that are not coordinated to boron. 
  Reference    Z. Naturforsch. 51b, 305—308 (1996); eingegangen am 28. September 1995 
  Published    1996 
  Keywords    Cobalt, Tin, Manganese, Borate Oxide, Crystal Structure 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0305.pdf 
 Identifier    ZNB-1996-51b-0305 
 Volume    51 
18Author    O. Sedello, Hk Müller-BuschbaumRequires cookie*
 Title    On the Crystal Structure o f (C u ,M n )3 66M o30 12  
 Abstract    Single crystals o f (Cu,M n)3 66M o 30 12 have been prepared in sealed copper tubes. X-ray investiga­ tions lead to orthorhombic symmetry, space group Dih-Pnm a, a = 5.1541(9), b = 10.788(2), c = 18.114(3)) Ä , Z = 4. (Cu,M n)366M o 30 12 is iso­ typic to NaCo2 31M o 30 12 and (C u,C o)3 75M o 30 12 with split positions for two o f the metals. 
  Reference    Z. Naturforsch. 51b, 447—449 (1996); eingegangen am 31. August 1995 
  Published    1996 
  Keywords    Copper, Manganese, Molybdenum Oxide, Crystal Structure 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0447_n.pdf 
 Identifier    ZNB-1996-51b-0447_n 
 Volume    51 
19Author    O. Sedello, Hk Müller-BuschbaumRequires cookie*
 Title    On the Crystal Structure of (Cu, M n )U M o 30 12  
 Abstract    Single crystals of (C u,M n)U M o30 12 have been prepared in sealed copper tubes. X-ray investiga­ tions lead to hexagonal symmetry, space group C|h-P63/m, a = 9.7895 (13), c = 6.202(1) A , z = 2. (C u ,M n)U M o30 12 is isotypic to CdThM o30 12. Calculations of the Coulomb terms o f lattice energy with respect to different oxidation states o f copper, molybdenum and uranium and the pre­ viously described pair of isotypic compounds of CdThM o30 12 to Na2ThRe60 24 are discussed. 
  Reference    Z. Naturforsch. 51b, 450—452 (1996); eingegangen am 5. September 1995 
  Published    1996 
  Keywords    Copper, Manganese, Uranium Molybdenum Oxide, Crystal Structure 
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 Identifier    ZNB-1996-51b-0450_n 
 Volume    51 
20Author    Utzolino, Karsten BluhmRequires cookie*
 Title    A nne  
 Abstract    The compounds M nCo(B20 ?) (I) and M nM g(B20 5) (II) were prepared by using B20 3 flux techniques in an argon atmosphere. X-ray investigations on single crystals showed triclinic symmetry, space group C' -P i, I: a = 320.94(10), b = 619.20(11), c = 939.0(2) pm, a = 104.38(2)°, ß = 90.76(2)°, 7 = 92.046(14)° and II: a = 318.97(7), b = 619.8(2), c = 936.7(2) pm, q = 104.47(2)°, ß = 90.60(2)°, 7 = 91.98(2)° Z = 2. Their structures are isotypic with C o2(B20 5). All metal ions are octahedrally coordinated by six oxygen atoms. The structures contain diborate anions B ^ 4 -. Each boron atom is threefold coordinated by oxygen. Synthese und Kristallstruktur von manganhaltigen Pyroboraten: MnCo(B20 5) und MnMg(B20 5) 
  Reference    Z. Naturforsch. 51b, 912—916 (1996); eingegangen am 25. Januar 1996 
  Published    1996 
  Keywords    Manganese, Cobalt Magnesium, Pyroborate Crystal Structure, X-Ray 
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 Identifier    ZNB-1996-51b-0912 
 Volume    51 
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