| | 1 | Author
| JohannW. Buchler, Christine Dreher, Lam Kiong, Lay | Requires cookie* | | | Title
| Metallkomplexe mit Tetrapyrrol-Liganden, XXVIII [1] Mononukleare Nitridomangan(V)-Porphyrine: die ersten Mangan-Stickstoff-Dreifachbindungen Metal Complexes with Tetrapyrrole Ligands, XXVIII [1] Mononuclear Nitridomanganese(V) Porphyrins: the First Manganese Nitrogen Triple Bonds  | | | | Abstract
| The first complexes containing a manganese-nitrogen triple bond, nitrido(octaethylpor-phinato)manganese(V) [MnN(OEP)]** and nitrido[meso-tetra(j9-tolyl)porphinato]man-ganese(V) [MnN(TTP)], are prepared by hypochlorite oxidation of the corresponding meth-oxomanganese(III) porphyrins, Mn(OEP)OMe and Mn(TTP)OMe, in the presence of am-monia. The red, pentacoordinated, diamagnetic species are identified by UV/VIS-, IR-, X H NMR, and mass spectra. While the isoelectronic oxochromium(IV) or oxomolyb-denum(IV) porphyrins behave as weak oxidants or reductants, respectively, the nitrido-manganese(V) unit in the square pyramidal environment is chemically remarkably stable. | | | |
Reference
| Z. Naturforsch. 37b, 1155—1162 (1982); eingegangen am 17. März 1982 | | | |
Published
| 1982 | | | |
Keywords
| Manganese Porphyrins, Nitridomanganese Complexes, Metal Nitrogen Triple Bonds | | | |
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| default:Reihe_B/37/ZNB-1982-37b-1155.pdf | | | | Identifier
| ZNB-1982-37b-1155 | | | | Volume
| 37 | |
| 2 | Author
| JohannWalter Buchler, Christine Dreher | Requires cookie* | | | Title
| Metallkomplexe mit Tetrapyrrol-Liganden, XXXIII [1] Darstellung von Azidochrom(III)-, Azidomangan(III)-und Azidoeisen(III)-Porphyrinen und deren Photolyse zu terminalen oder verbrückten Nitridometallporphyrinen Metal Complexes with Tetrapyrrole Ligands XXXIII [1] Preparation of Azidochromium(III)-, Azidomanganese(III)-, and Azidoiron(III) Porphyrins and their Photolysis to Terminal or Bridged Nitridometal Porphyrins | | | | Abstract
| Azidometal(III) porphyrins, e.g. M(TTP)N3 lA a— ICa (M = Cr, Mn, Fe), are transformed | | | |
Reference
| Z. Naturforsch. 39b, 222 (1984); eingegangen am 29. August 1983 | | | |
Published
| 1984 | | | |
Keywords
| Chromium Porphyrins, Manganese Porphyrins, Nitridometal Complexes, Photolysis of Azido Complexes | | | |
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| default:Reihe_B/39/ZNB-1984-39b-0222.pdf | | | | Identifier
| ZNB-1984-39b-0222 | | | | Volume
| 39 | |
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