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1984 (1)
1982 (1)
1Author    JohannW. Buchler, Christine Dreher, Lam Kiong, LayRequires cookie*
 Title    Metallkomplexe mit Tetrapyrrol-Liganden, XXVIII [1] Mononukleare Nitridomangan(V)-Porphyrine: die ersten Mangan-Stickstoff-Dreifachbindungen Metal Complexes with Tetrapyrrole Ligands, XXVIII [1] Mononuclear Nitridomanganese(V) Porphyrins: the First Manganese Nitrogen Triple Bonds  
 Abstract    The first complexes containing a manganese-nitrogen triple bond, nitrido(octaethylpor-phinato)manganese(V) [MnN(OEP)]** and nitrido[meso-tetra(j9-tolyl)porphinato]man-ganese(V) [MnN(TTP)], are prepared by hypochlorite oxidation of the corresponding meth-oxomanganese(III) porphyrins, Mn(OEP)OMe and Mn(TTP)OMe, in the presence of am-monia. The red, pentacoordinated, diamagnetic species are identified by UV/VIS-, IR-, X H NMR, and mass spectra. While the isoelectronic oxochromium(IV) or oxomolyb-denum(IV) porphyrins behave as weak oxidants or reductants, respectively, the nitrido-manganese(V) unit in the square pyramidal environment is chemically remarkably stable. 
  Reference    Z. Naturforsch. 37b, 1155—1162 (1982); eingegangen am 17. März 1982 
  Published    1982 
  Keywords    Manganese Porphyrins, Nitridomanganese Complexes, Metal Nitrogen Triple Bonds 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1155.pdf 
 Identifier    ZNB-1982-37b-1155 
 Volume    37 
2Author    JohannWalter Buchler, Christine DreherRequires cookie*
 Title    Metallkomplexe mit Tetrapyrrol-Liganden, XXXIII [1] Darstellung von Azidochrom(III)-, Azidomangan(III)-und Azidoeisen(III)-Porphyrinen und deren Photolyse zu terminalen oder verbrückten Nitridometallporphyrinen Metal Complexes with Tetrapyrrole Ligands XXXIII [1] Preparation of Azidochromium(III)-, Azidomanganese(III)-, and Azidoiron(III) Porphyrins and their Photolysis to Terminal or Bridged Nitridometal Porphyrins  
 Abstract    Azidometal(III) porphyrins, e.g. M(TTP)N3 lA a— ICa (M = Cr, Mn, Fe), are transformed 
  Reference    Z. Naturforsch. 39b, 222 (1984); eingegangen am 29. August 1983 
  Published    1984 
  Keywords    Chromium Porphyrins, Manganese Porphyrins, Nitridometal Complexes, Photolysis of Azido Complexes 
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 TEI-XML for    default:Reihe_B/39/ZNB-1984-39b-0222.pdf 
 Identifier    ZNB-1984-39b-0222 
 Volume    39