| | 1 | Author
| YalcinE. Lerm Ana+, MehmetK. Abaka, Ingrid Svobodab, H. Artm Ut Fuessb-, KlausG. Riesarc, WolfgangH. Aasec | Requires cookie* | | | Title
| X-Ray Structure and Magnetic Properties of the Tetracupferronato-bis(//-methoxy)-diiron(III) Complex  | | | | Abstract
| The tetracupferronato-bis(w-methoxy)-diiron(III) complex has been synthesized in aceto nitrile and its crystal structure determined. C i6H->6N80 1(>Fe2, monoclinic, space group C2/c, a =18.425(3), b = 12.999(2), c = 15.046(3) A, ß = 12 4 .6 6 (2)°,> = 2964(1) A , Z = 4, wR(2) = 0.097 from 1491 reflections (F2). Two iron(III) atoms are at special positions in six-fold co ordination, bridged by O with a F e -O -F e angle of 102.4(1)° and a distance between two iron(III) centers of 3.075(1) A. Temperature-dependent magnetic susceptibility measure ments reveal a antiferromagnetic exchange interaction (J = -1 4 cm -1) betw een the iron(III) centers. | | | |
Reference
| Z. Naturforsch. 50b, 1587—1590 (1995); received January 11 1995 | | | |
Published
| 1995 | | | |
Keywords
| X -Ray, Magnetic Properties, Antiferromagnetic Coupling | | | |
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