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'Magnetic Exchange' in keywords Facet   Publication Year 1981  [X]
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1981[X]
1Author    Ger Vos, JaapG. Haasnoot, WillemL. GroeneveldRequires cookie*
 Title    Complexes of 1,2,4-Triazoles, Part XVI Binuclear Complexes of Transition Metal(II)thiocyanates with 4-Ethyl-l,2,4-triazole  
 Abstract    Coordination compounds of 4-ethyl-l,2,4-triazole (Ettrz) with Mn, Fe, Co, Ni, Cu and Zn are reported. The compounds have been identified and characterized by chemical analyses, infrared and ligand field spectra, electron paramagnetic resonance (e.p.r.) measurements, magnetic susceptibility measurements and thermoanalytical experiments. Except for the Cu compound, which is polynuclear, all compounds appear to be binuclear, with both bridging bidentate and non-bridging triazole ligands. The overall formula is M(Ettrz)2(NCS)2(H20)3/2 for Mn, Fe, Co and Ni. The copper and zinc compounds have the formula Cu(Ettrz)2(NCS)2 and Zn(Ettrz)3/2(NCS)2. 
  Reference    Z. Naturforsch. 36b, 802—808 (1981); received March 2 1981 
  Published    1981 
  Keywords    4-Ethyl-l, 2, 4-triazole, Ligand Field, Magnetic Exchange, Binuclear Complexes 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0802.pdf 
 Identifier    ZNB-1981-36b-0802 
 Volume    36