1 | Author | Erwin Riedel, Hümeyra Anik, Till Dützmann | Requires cookie* |
Title | Verteilung und Valenz der Kationen in Spinellsystemen mit Eisen und Vanadium, III Röntgenographische und Mößbauer-spektroskopische Untersuchung des Spinellsystems ZnFeV04-Fe304 Distribution and Valence of the Cations in Spinel Systems with Iron and Vanadium, III X-ray Investigation and Mössbauer Spectra of the Spinel System ZnFeV04-Fe304 ![]() | ||
Abstract | The spinel system Zni_zFe2:[Fei+2;Vi_I]04 has been prepared by heating mixtures of ZnFeV(>4 and Fe3Ü4 at 1000 °C. The lattice constants, the oxygen parameters and the Mössbauer parameters show that a transition from a nearly normal to an inverse distribu-tion of Fe(II) and Fe(III) exists. | ||
Reference | Z. Naturforsch. 36b, 1228—1233 (1981); eingegangen am 4. Mai 1981 | ||
Published | 1981 | ||
Keywords | Zinc-Iron-Vanadium Spineis, Mössbauer Spectroscopy, Valence Distribution, Charge Hopping | ||
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