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'M olybdenum' in keywords Facet   Publication Year 1993  [X]
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1993[X]
1Author    Saim Özkar, Zahide ÖzerRequires cookie*
 Title    3C NMR Spectroscopic Study of Pentacarbonylacetonitrilemetal(O) Complexes of the Group 6 B Elements  
 Abstract    The com plexes M (CO)5(C H 3C N) (M: Cr, M o, W) were obtained from the substitution o f TH F in M (C O)5(TH F) which has been generated by photolysis o f M(CO)6 in T H F and characterized by using IR , 'H N M R and l3C N M R spectrosco­ pies. The acetonitrile ligand is found to be N -bonded to the M (CO)5-moiety with a local C4v-symmetry. The effect o f the acetonitrile ligand on the metal-carbonyl bonding was discussed in terms o f l3C N M R chemical shifts. 
  Reference    Z. Naturforsch. 48b, 1431 (1993); received M ay 17 1993 
  Published    1993 
  Keywords    Chromium, M olybdenum, Tungsten, Carbonyl, Acetonitrile 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-1431_n.pdf 
 Identifier    ZNB-1993-48b-1431_n 
 Volume    48