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'M olybdenum Complexes' in keywords
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1995 (1)
1994 (1)
1Author    ProfRequires cookie*
 Title    Funktionalisierte tripod-Liganden mit Neopentan-Grundgerüst: Umsetzung von HOCH2C(CH2PR 2)3 mit Elektrophilen  
 Abstract    Several ways to functionalize hydroxy-rn'pod-ligands (H O C H 2C (C H 2PR2)3) by activation with electrophiles are presented. The use o f carboxylic halides and anhydrides is shown to be generally successful for esterification reactions in a one-pot synthesis starting from the oxetanes 0 (C H 2)2C(CH2PR2)2. Facial coordinaton of the related esters towards iron(II) and molybdenum(O) can be achieved depending on the nature of the phosphane donor groups. If methyliodide or trimethylsilylchloride are used as electrophiles in order to functionalize the hydroxy group in H O CH 2C (CH 2PR2)3, it is necessary to proctect the phosphane groups by formation of the tris-borane adduct. All new compounds have been fully characterized by the usual analytical techniques as well as by X-ray analyses on selected examples. 
  Reference    Z. Naturforsch. 50b, 1287—1306 (1995); eingegangen am 20. Januar 1995 
  Published    1995 
  Keywords    Functionalized Neopentane Compound, Esterification, Phosphane-Boranes, Iron Complexes, M olybdenum Complexes 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1287.pdf 
 Identifier    ZNB-1995-50b-1287 
 Volume    50 
2Author    Axel Fischer, Ion Neda, PeterG. Jones, Reinhard SchmutzlerRequires cookie*
 Title    Darstellung und Kristallstrukturen einiger Ubergangsmetall-Komplexverbindungen mit Liganden mit dem 4,5-Benzo-3-methyl-l,3?2-oxazaphosphorinan-6-on-Gerüst Synthesis and X-Ray Crystal Structures of Some Transition-Metal Complexes Involving Ligands with the 4,5-Benzo-3-methyl-l,3,2-oxazaphosphorinan-6-one Framework  
  Reference    Z. Naturforsch. 49b, 1481—1493 (1994); eingegangen am 21. Februar 1994 
  Published    1994 
  Keywords    2-Substituted 4, 5-Benzo-3-m ethyl-l, 3, 2-oxazaphosphorinan-6-ones Ligands, Platinum Complexes, M olybdenum Complexes, Single Crystal X-Ray Structure Analysis 
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 TEI-XML for    default:Reihe_B/49/ZNB-1994-49b-1481.pdf 
 Identifier    ZNB-1994-49b-1481 
 Volume    49