| 1 | Author | WolfgangA H Errm Ann, JosefK. Felixberger, JosefG. Kuchler, Eberhardt Herdtweck | Requires cookie* |
| Title | Alkin-Komplexe des Rheniums in hohen Oxidationsstufen Alkyne Complexes of Rhenium in High Oxidation States  | ||
| Abstract | The class o f ^-alkyne complexes o f metals in medium and high oxidation states has been extended by the type C H 3R e 0 2(R C = C R) (3a-i). Exchange o f alkyne for oxo ligands under reducing conditions has been employed as a new general synthesis. C om pounds 3 are thus ob tained by reaction o f methyltrioxorhenium(VII) (1) with the alkynes 2 a -i in the presence o f a ca. 1.1-fold molar amount o f polymer-bound triphenylphosphane as reducing agent ( | ||
| Reference | Z. Naturforsch. 45b, 876—8 (1990); eingegangen am 30. N ovem ber 1989 | ||
| Published | 1990 | ||
| Keywords | M ethyloxorhenium Alkynes, Synthesis, Crystal Structures | ||
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