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'M ethyloxorhenium Alkynes' in keywords
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1990 (1)
1Author    WolfgangA H Errm Ann, JosefK. Felixberger, JosefG. Kuchler, Eberhardt HerdtweckRequires cookie*
 Title    Alkin-Komplexe des Rheniums in hohen Oxidationsstufen Alkyne Complexes of Rhenium in High Oxidation States  
 Abstract    The class o f ^-alkyne complexes o f metals in medium and high oxidation states has been extended by the type C H 3R e 0 2(R C = C R) (3a-i). Exchange o f alkyne for oxo ligands under reducing conditions has been employed as a new general synthesis. C om pounds 3 are thus ob­ tained by reaction o f methyltrioxorhenium(VII) (1) with the alkynes 2 a -i in the presence o f a ca. 1.1-fold molar amount o f polymer-bound triphenylphosphane as reducing agent ( 
  Reference    Z. Naturforsch. 45b, 876—8 (1990); eingegangen am 30. N ovem ber 1989 
  Published    1990 
  Keywords    M ethyloxorhenium Alkynes, Synthesis, Crystal Structures 
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 TEI-XML for    default:Reihe_B/45/ZNB-1990-45b-0876.pdf 
 Identifier    ZNB-1990-45b-0876 
 Volume    45