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'Lobry de Bruyn van Ekenstein Rearrangement' in keywords
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1983 (1)
1Author    Günther Harsch, Monika Harsch, Hermann Bauer, Wolfgang VoelterRequires cookie*
 Title    Produktverteilung und Mechanismus der Gesamtreaktion der Formose-Reaktion Product Analysis and Mechanism of the Formose Reaction  
 Abstract    By means of liquid chromatographic analysis, UV, 13 C NMR and GC-MS spectroscopy it is possible to determine quantitatively the most important intermediate and final products of the formose reaction. As stable main products xylose, glucose and dendro-ketose, as stable side products ribose, lyxose, arabinose, mannose, dendroaldose, fructose and sorbose are identified. Instable intermediates are glycolaldehyde, glycerolaldehyde, dihydroxiacetone, erythrose, threose and pentuloses. Cannizzaro reaction, oligomerization and the primary formose reaction are catalyzed by a calcium hydroxide bismethylene glycolate complex. 
  Reference    Z. Naturforsch. 38b, 1269—1280 (1983); eingegangen am 26. Mai 1983 
  Published    1983 
  Keywords    Formose Reaction, Autocatalysis, Cannizzaro Reaction, Lobry-de-Bruyn-van-Ekenstein Rearrangement 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-1269.pdf 
 Identifier    ZNB-1983-38b-1269 
 Volume    38