| | 1 | Author
| Günther Harsch, Monika Harsch, Hermann Bauer, Wolfgang Voelter | Requires cookie* | | | Title
| Produktverteilung und Mechanismus der Gesamtreaktion der Formose-Reaktion Product Analysis and Mechanism of the Formose Reaction  | | | | Abstract
| By means of liquid chromatographic analysis, UV, 13 C NMR and GC-MS spectroscopy it is possible to determine quantitatively the most important intermediate and final products of the formose reaction. As stable main products xylose, glucose and dendro-ketose, as stable side products ribose, lyxose, arabinose, mannose, dendroaldose, fructose and sorbose are identified. Instable intermediates are glycolaldehyde, glycerolaldehyde, dihydroxiacetone, erythrose, threose and pentuloses. Cannizzaro reaction, oligomerization and the primary formose reaction are catalyzed by a calcium hydroxide bismethylene glycolate complex. | | | |
Reference
| Z. Naturforsch. 38b, 1269—1280 (1983); eingegangen am 26. Mai 1983 | | | |
Published
| 1983 | | | |
Keywords
| Formose Reaction, Autocatalysis, Cannizzaro Reaction, Lobry-de-Bruyn-van-Ekenstein Rearrangement | | | |
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| default:Reihe_B/38/ZNB-1983-38b-1269.pdf | | | | Identifier
| ZNB-1983-38b-1269 | | | | Volume
| 38 | |
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