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'Lithium Ozonide Ammonia' in keywords Facet   section ZfN Section B  [X]
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1999 (1)
1Author    Wilhelm Klein3, Martin JansenbRequires cookie*
 Title    Darstellung und Kristallstruktur von Lithiumozonid-Ammoniakat (1/5) Li(> 3 * 5 NH3 Synthesis and Crystal Structure of Lithiumozonide-Ammonia (1/5) L i0 3 * 5 NH3  
 Abstract    Lithium ozonide has been synthezised starting from cesium ozonide via cation exchange in liquid ammonia and crystallizes at -78°C as an ammoniate, L i0 3 • 5NH3. The coarse, ruby red crystals decompose above the boiling temperature of ammonia and are extremely sensitive to moisture. The crystal structure of L i0 3 • 5NH3 (P c2\n; a = 1231.9(5), b = 637.4(2), c = 1104.8(4) pm; Z = 4; /?, = 4.57%; 1318 independent reflections) consists of lithium tetramine complexes, ozonide anions and non coordinating ammonia molecules. With respect to the arrangement of the complex cations and of the anions there is similarity to the WC type of structure. The central oxygen atom of the ozonide anion is disordered. 
  Reference    Z. Naturforsch. 54b, 1345—1349 (1999); eingegangen am 28. Juni 1999 
  Published    1999 
  Keywords    Lithium Ozonide Ammonia, Ionic Ozonides, Lithium Tetramine Complex, Crystal Structure 
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 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-1345.pdf 
 Identifier    ZNB-1999-54b-1345 
 Volume    54