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'Lithium Chromium Chloride' in keywords
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1992 (1)
1Author    HeinzDieter Lutz, Peter Kuske, Arno Pfltzner, Herm Ann-, Josef Steiner, Herrn Prof, Dr, Hanns-PeterRequires cookie*
 Title    Kristallstruktur und Schwingungsspektren von Li5CrCl8 Crystal Structure and Vibrational Spectra of Li5C rC l8  
 Abstract    The crystal structure o f the novel pink Li5CrClg oC 28 has been determined by both single crystal X-ray and neutron powder studies. The title com pound crystallizes in a hitherto un­ known structure type (space group C m m m , Z = 2). The final R values are R = 3.4% (715 independent reflections with I > 2>ax) and Rwp = 11.5%, respectively (a = 1019.79(3), b = 723.94(2) and c = 726.16(3) pm). The structure consists o f edge-connected L i(l)C l6 and alter­ nating edge-connected Li(2)Cl6 and CrCl6 octahedra, respectively. It is related to the N aCl su­ per structure SnM n2S4 type. IR and Raman spectra as well as symmetry coordinates are given and discussed in terms o f CrCl6 and LiCl6 breathing modes. 
  Reference    Z. Naturforsch. 47b, 1687—1692 (1992); eingegangen am 1. Juni 1992 
  Published    1992 
  Keywords    Lithium Chromium Chloride, Crystal Structure, Raman Spectra 
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 TEI-XML for    default:Reihe_B/47/ZNB-1992-47b-1687.pdf 
 Identifier    ZNB-1992-47b-1687 
 Volume    47