| | 1 | Author
| HeinzDieter Lutz, Peter Kuske, Arno Pfltzner, Herm Ann-, Josef Steiner, Herrn Prof, Dr, Hanns-Peter | Requires cookie* | | | Title
| Kristallstruktur und Schwingungsspektren von Li5CrCl8 Crystal Structure and Vibrational Spectra of Li5C rC l8  | | | | Abstract
| The crystal structure o f the novel pink Li5CrClg oC 28 has been determined by both single crystal X-ray and neutron powder studies. The title com pound crystallizes in a hitherto un known structure type (space group C m m m , Z = 2). The final R values are R = 3.4% (715 independent reflections with I > 2>ax) and Rwp = 11.5%, respectively (a = 1019.79(3), b = 723.94(2) and c = 726.16(3) pm). The structure consists o f edge-connected L i(l)C l6 and alter nating edge-connected Li(2)Cl6 and CrCl6 octahedra, respectively. It is related to the N aCl su per structure SnM n2S4 type. IR and Raman spectra as well as symmetry coordinates are given and discussed in terms o f CrCl6 and LiCl6 breathing modes. | | | |
Reference
| Z. Naturforsch. 47b, 1687—1692 (1992); eingegangen am 1. Juni 1992 | | | |
Published
| 1992 | | | |
Keywords
| Lithium Chromium Chloride, Crystal Structure, Raman Spectra | | | |
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| default:Reihe_B/47/ZNB-1992-47b-1687.pdf | | | | Identifier
| ZNB-1992-47b-1687 | | | | Volume
| 47 | |
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