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1997 (1)
1Author    Toshiyuki Takamuku, Motoyuki Yamagami, Hisanobu Wakita, Toshio YamaguchiRequires cookie*
 Title    X-ray Diffraction Studies on Supercooled Aqueous Lithium Bromide and Lithium Iodide Solutions  
 Abstract    X-ray diffraction measurements were performed on liquid LiBr • 5H 2 0 and Lil • 5H 2 0 at tem-peratures from —30 to 25 °C. The total radial distribution functions did show that on supercooling the hydration shell of the halide ions becomes more structured, while that of the lithium ions becomes distorted. The larger the halide ion, the stronger becomes the water-water interaction around halide ions with lowering temperature. However, the distance between the water molecules in the hydration shells of the halide ions depends little on their size. On the basis of the present results, together with those of our previous investigation on LiCl • 5H 2 0 at temperatures from — 135 to 100°C, the effects of temperature and the size of the halide ions on the structure of the solution are discussed. 
  Reference    Z. Naturforsch. 52a, 521—527 (1997); received March 13 1997 
  Published    1997 
  Keywords    Lithium Bromide, Lithium Iodide, X-ray diffraction, Supercooled temperature, Hydra-tion structure 
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 TEI-XML for    default:Reihe_A/52/ZNA-1997-52a-0521.pdf 
 Identifier    ZNA-1997-52a-0521 
 Volume    52