| | 1 | Author
| Evamarie Hey-Hawkins+, Stefan Kurz, G.Erhard Baum | Requires cookie* | | | Title
| P-H-funktionelle Zirkonocen-Phosphido-Komplexe  | | | | Abstract
| Synthese von Cp'2Zr{PH(2,4,6-Pr'3C6H2)}(X) (Cp = C5H4Me, X = Cl, 2,4,6-Pr'3C6H2) und Molekülstruktur von Cp'2ZrCl{PH(2,4,6-Pr/3C6H2)} P-H -Functionalized Zirconocene Phosphido Complexes -Synthesis of C p '2Zr{PH(2,4,6-Pr'3C6H 2)}(X) (Cp' = C5H 4 Me, X = Cl, 2,4,6-Pr'3C6H 2) and Molecular Structure of C p '2ZrCl{PH(2,4,6-Pr'3C6H 2)} The reaction of Cp'2ZrCl2 (Cp' = C5H4M e) with solvent-free LiPH(2,4,6-Pr'3C6H 2) yields the terminal zirconocene phosphido com plexes Cp'2ZrCl{PH(2,4,6-Pr'3C6H 2)} (1) (1:1 reac tion) or Cp'2Zr{PH(2,4,6-Pr'3C6H2)}2 (2) (1:2 reaction). 1 and 2 were characterized spectro scopically (NMR, IR, MS). An X-ray structure determination was carried out on 1 (Z r -P 2.6381(8) A, Z r-C l 2.4547(6) A , C l-Z r -P 93.55(2)°). | | | |
Reference
| Z. Naturforsch. 50b, 239 (1995); eingegangen am 15. Septem ber 1994 | | | |
Published
| 1995 | | | |
Keywords
| Zirconocene Phosphido Complexes, Lithium 2, 4, 6-Triisopropylphenylphosphide, Crystal Structure | | | |
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| default:Reihe_B/50/ZNB-1995-50b-0239.pdf | | | | Identifier
| ZNB-1995-50b-0239 | | | | Volume
| 50 | |
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