| 1 | Author | Uwe Klingebiel | Requires cookie* |
| Title | Reaktionen von Lithio-aminofluorsilanen mit Halogensilanen und Trimethylzinnchlorid Reactions of Lithio-aminofluorosilanes with Halogensilanes and Trimethyltinchloride  | ||
| Abstract | Fluorosilanes react with lithium amides and organolithium compounds to give amino-fluorosilanes. (Lithioamino)fluorosilanes are formed by the reaction of aminofluoro-silanes with butyllithium depending on the steric influence and molecular stabilization of the ligands. These lithium salts react with halogensilanes and trimethyltin chloride with substitution. By LiF elimination the lithio-aminofluorosilane C6H5-SiF-NLiC(CH3)3-N(p-C6H4CH3Si(CH3)3) cyclisizes through a (2-j-2)cycloaddition and SiC-H-cleavage. | ||
| Reference | Z. Naturforsch. 33b, 521—526 (1978); eingegangen am 3. Januar/21. Februar 1978 | ||
| Published | 1978 | ||
| Keywords | Lithio-aminofluorosilanes, Substitution, Cyclisation, NMR | ||
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