| | 1 | Author
| CyR. Il, P., G. In, J. L. | Requires cookie* | | | Title
| Charge-Transfer Spectra of Some Heterocyclic Cations  | | | | Abstract
| Energies of the first charge-transfer bands of complexes of heterocyclic pyridi-nium-like cations with various electron donors (the iodide ion, benzenoid h ydro carbons) yield linear correlations with the HMO energies of the lowest unoccupied rr-molecular orbitals (LUMO) o f the hetero cyclic acceptors. The experimental charge-transfer band maxima were taken from the literature. Charge-transfer band maxima for the complexes of the 2,4,6-trim ethylpyrylium cation with several electrons donors (diethyl-amine, N,N-dimethylaniline, pyridine N-oxide, anthracene) have been determined and compared with the analogous data for the tropylium cation. | | | |
Reference
| (Z. Naturforsch. 30b, 984—986 [1975]; received June 23 1975) | | | |
Published
| 1975 | | | |
Keywords
| N-Methylpyridinium-like Cations, Tropylium Cation, 2, 4, 6-Trim ethylpyrylium Cation, HMO Calculations, Linear Correlations | | | |
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| default:Reihe_B/30/ZNB-1975-30b-0984_n.pdf | | | | Identifier
| ZNB-1975-30b-0984_n | | | | Volume
| 30 | |
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