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'Linear Correlations' in keywords Facet   Publication Year 1975  [X]
Facet   section ZfN Section B  [X]
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1Author    CyR. Il, P., G. In, J. L.Requires cookie*
 Title    Charge-Transfer Spectra of Some Heterocyclic Cations  
 Abstract    Energies of the first charge-transfer bands of complexes of heterocyclic pyridi-nium-like cations with various electron donors (the iodide ion, benzenoid h ydro­ carbons) yield linear correlations with the HMO energies of the lowest unoccupied rr-molecular orbitals (LUMO) o f the hetero­ cyclic acceptors. The experimental charge-transfer band maxima were taken from the literature. Charge-transfer band maxima for the complexes of the 2,4,6-trim ethylpyrylium cation with several electrons donors (diethyl-amine, N,N-dimethylaniline, pyridine N-oxide, anthracene) have been determined and compared with the analogous data for the tropylium cation. 
  Reference    (Z. Naturforsch. 30b, 984—986 [1975]; received June 23 1975) 
  Published    1975 
  Keywords    N-Methylpyridinium-like Cations, Tropylium Cation, 2, 4, 6-Trim ethylpyrylium Cation, HMO Calculations, Linear Correlations 
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 TEI-XML for    default:Reihe_B/30/ZNB-1975-30b-0984_n.pdf 
 Identifier    ZNB-1975-30b-0984_n 
 Volume    30