| 1 | Author
| H. Endres, H. J. Keller, R. Martin, S. Nötzel | Requires cookie* | | Title
| Crystal and Molecular Structure of the Linear Chain Bis(l,2-diaminopropane)platinum(II,rV)tribromide  | | | Abstract
| [Pt(dapn)2]Br3 (dapn = 1,2-diaminopropane), ortho-rhombic, Immm (Dfj>), a = 5.338(1), b = 6.900(5), c= 19.738(4) A, Z = 2, V= 727 Ä 3 , dc = 2.7 g • cm~ 3 . The structure was refined to R = 0.094 for 576 reflections and can be described as a Wolffram's salt analogue. A rotating crystal photograph shows weak diffuse layers between the Bragg reflections as evidence for one-dimensional order along the M-X-M chain, but for successful refine-ment the M-X distance (2.673(1) A) have to be assumed to be equal. | | |
Reference
| Z. Naturforsch. 35b, 1274—1276 (1980); received May 9 1980 | | |
Published
| 1980 | | |
Keywords
| Wolffram's Salt Analogue, Platinum Complex, Linear Bromide Bridges | | |
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| default:Reihe_B/35/ZNB-1980-35b-1274.pdf | | | Identifier
| ZNB-1980-35b-1274 | | | Volume
| 35 | |
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