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'Ligand Field Spectra' in keywords Facet   section ZfN Section B:Volume 034  [X]
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1979 (1)
1Author    Eberhard Stumpp, Uwe HillebrandRequires cookie*
 Title    Ligandenfeldspektroskopische Untersuchungen an Übergangsmetall -Aluminium -Tetraalkoxiden Ligand Field Spectroscopic Studies of Transition Metal Aluminium-Tetraalkoxides  
 Abstract    The preparation and the electronic spectral properties of compounds M[A1(0R)4]2 (M = Co, Ni, Cu and R = CH3, C2H5, n-CsIU, n-CjHg) are described. The spectral data are used in conjunction with ligand field theory in deducing the structures of the compounds. The spectrum of green Ni[Al(OR)4]2 is interpreted as a Ni(OR)6 octahedron sharing faces with two Al(OR)4 tetrahedrons. It is proposed that Co 2+ and Cu 2+ are in a distorted octahedral coordination. The alkoxide ligands have been fitted into the spectrochemical and the nephelauxetic series. They are close to H2O in this series. 
  Reference    Z. Naturforsch. 34b, 262—265 (1979); eingegangen am 9. 0ktober/20. November 1978 
  Published    1979 
  Keywords    Transition Metal Aluminium-Tetraalkoxides, Ligand Field Spectra, Molecular Structure, Spectrochemical Series, Nephelauxetic Series 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-0262.pdf 
 Identifier    ZNB-1979-34b-0262 
 Volume    34