| 1 | Author
| Wolfgang Malisch, Peter Panster, Robert Alsmann | Requires cookie* | | Title
| Transition Metal Substituted VB Element Systems, 12 [1] Mono-and Dinuclear Transition Metal Complexes with Dihalogenarsenic Groups  | | | Abstract
| The reaction of ASCI3 with the transition metal anions [r^-CsHstCO^M] 9 (M = Cr, Mo, W) yields the arsenic transition metal complexes -C5H5(CO)3M-AsCl2, which readily form Jrans-77 5 -C5H5(CO)2LM-AsCl2 in the presence of phosphorus donors [L = P(OCH3)3, P(CH3)2C6H5]. Addition of M(CO)s-groups on the trivalent arsenic occurs with THF • M'(CO)s (M' = Cr, Mo) leading to the arsenic bridged dinuclear complexes ^-CsHstCO^Cr-AsC^M^CO^. Controlled Cl/F-exchange at the bridged species can be achieved by use of AgBF4. | | |
Reference
| Z. Naturforsch. 33b, 899—905 (1978); eingegangen am 21. Juni 1978 | | |
Published
| 1978 | | |
Keywords
| Arsenic Transition Metal Complexes, Ligand Exchange, Dinuclear Complexes | | |
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| default:Reihe_B/33/ZNB-1978-33b-0899.pdf | | | Identifier
| ZNB-1978-33b-0899 | | | Volume
| 33 | |
2 | Author
| UlrichW. Gerwarth | Requires cookie* | | Title
| Borverbindungen, 12. Mitteilung Das Kristallisationsverhalten der Poly(2-phenyl-1.3.2-dioxabora-cycloalkane) Boron Compounds, Part 12 The Crystallizing Behaviour of Poly(2-phenyl-l,3,2-dioxybora-cycloalkanes)  | | |
Reference
| Z. Naturforsch. 34b, 1084—1091 (1979); eingegangen am 4. April 1979 | | |
Published
| 1979 | | |
Keywords
| 1, 3, 2-Dioxybora-cycloalkanes, Ligand Exchange, Metathetic Rearrangement, Cyclic Oligomers, Thermal Analysis | | |
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| default:Reihe_B/34/ZNB-1979-34b-1084.pdf | | | Identifier
| ZNB-1979-34b-1084 | | | Volume
| 34 | |
3 | Author
| W. Banßea, J. Fliegner3, H. Hennigb, A. Lehmannc, I. Starked, F. Tschwatschalb, E. Uhlemann3 ' | Requires cookie* | | Title
| Ligandenaustauschreaktionen von Molybdänhexacarbonyl mit dreizähnigen diaciden Liganden Ligand Exchange Reactions of Molybdenum Hexacarbonyl with Tridentate Diacidic Ligands  | | | Abstract
| Ligand exchange reactions of molybdenum hexacarbonyl with tridentate diacidic ligands were studied by means of photochemical and thermal activation. The reaction products were characterized by mass spectrometry. Species such as MoL2, MoH2L2 and M o02L could be identified. | | |
Reference
| Z. Naturforsch. 52b, 1077—1081 (1997); eingegangen am 11. Juli 1997 | | |
Published
| 1997 | | |
Keywords
| Ligand Exchange, Molybdenum Hexacarbonyl, Tridentate Diacidic Ligands, Photochemical and Thermal Decarbonylation | | |
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| default:Reihe_B/52/ZNB-1997-52b-1077.pdf | | | Identifier
| ZNB-1997-52b-1077 | | | Volume
| 52 | |
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