| | 1 | Author
| Wolfgang Malisch, Peter Panster, Robert Alsmann | Requires cookie* | | | Title
| Transition Metal Substituted VB Element Systems, 12 [1] Mono-and Dinuclear Transition Metal Complexes with Dihalogenarsenic Groups  | | | | Abstract
| The reaction of ASCI3 with the transition metal anions [r^-CsHstCO^M] 9 (M = Cr, Mo, W) yields the arsenic transition metal complexes -C5H5(CO)3M-AsCl2, which readily form Jrans-77 5 -C5H5(CO)2LM-AsCl2 in the presence of phosphorus donors [L = P(OCH3)3, P(CH3)2C6H5]. Addition of M(CO)s-groups on the trivalent arsenic occurs with THF • M'(CO)s (M' = Cr, Mo) leading to the arsenic bridged dinuclear complexes ^-CsHstCO^Cr-AsC^M^CO^. Controlled Cl/F-exchange at the bridged species can be achieved by use of AgBF4. | | | |
Reference
| Z. Naturforsch. 33b, 899—905 (1978); eingegangen am 21. Juni 1978 | | | |
Published
| 1978 | | | |
Keywords
| Arsenic Transition Metal Complexes, Ligand Exchange, Dinuclear Complexes | | | |
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| default:Reihe_B/33/ZNB-1978-33b-0899.pdf | | | | Identifier
| ZNB-1978-33b-0899 | | | | Volume
| 33 | |
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