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'Ligand Exchange' in keywords Facet   Publication Year 1978  [X]
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1Author    Wolfgang Malisch, Peter Panster, Robert AlsmannRequires cookie*
 Title    Transition Metal Substituted VB Element Systems, 12 [1] Mono-and Dinuclear Transition Metal Complexes with Dihalogenarsenic Groups  
 Abstract    The reaction of ASCI3 with the transition metal anions [r^-CsHstCO^M] 9 (M = Cr, Mo, W) yields the arsenic transition metal complexes -C5H5(CO)3M-AsCl2, which readily form Jrans-77 5 -C5H5(CO)2LM-AsCl2 in the presence of phosphorus donors [L = P(OCH3)3, P(CH3)2C6H5]. Addition of M(CO)s-groups on the trivalent arsenic occurs with THF • M'(CO)s (M' = Cr, Mo) leading to the arsenic bridged dinuclear complexes ^-CsHstCO^Cr-AsC^M^CO^. Controlled Cl/F-exchange at the bridged species can be achieved by use of AgBF4. 
  Reference    Z. Naturforsch. 33b, 899—905 (1978); eingegangen am 21. Juni 1978 
  Published    1978 
  Keywords    Arsenic Transition Metal Complexes, Ligand Exchange, Dinuclear Complexes 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0899.pdf 
 Identifier    ZNB-1978-33b-0899 
 Volume    33