1 | Author | F. Rank Schrumpf, HerbertW. Roesky+, M. Athias Noltemeyer | Requires cookie* |
Title | ( rf-C5Me5)T a F4 * H N = P Ph3 Preparation and Structure of the Adduct (7 5-C5M e5)TaF4 * HN = PPh3 ![]() | ||
Abstract | C p*TaF4 (1) (Cp* = ^5-C5M e5) forms a Lewis acid Lewis base adduct with the im inophos phorane H N = PPh3 (2). The adduct C p*TaF4-N H = PPh3 (3) is remarkably stable to thermal decom position. The X-ray crystal struc ture o f 3 was investigated. | ||
Reference | Z. Naturforsch. 45b, 1600—1602 (1990); eingegangen am 7. Juni 1990 | ||
Published | 1990 | ||
Keywords | Tantalum Fluoride, Lewis Acidity, Iminophosphorane, X-Ray Structure | ||
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